[(S)-[8-[8-[(S)-[(2S)-2-methoxy-2-phenylacetyl]oxy-phenylmethyl]naphthalen-1-yl]oxynaphthalen-1-yl]-phenylmethyl] (2S)-2-methoxy-2-phenylacetate | 204583-83-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [(S)-[8-[8-[(S)-[(2S)-2-methoxy-2-phenylacetyl]oxy-phenylmethyl]naphthalen-1-yl]oxynaphthalen-1-yl]-phenylmethyl] (2S)-2-methoxy-2-phenylacetate
• CAS: 204583-83-5
• 化学式: C₅₂H₄₂O₇
• 分子量: 778.901
• InChiKey: MNORDWNTFRXOJE-SIAPTGDMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.9
• 重原子数：
  59
• 可旋转键数：
  16
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  80.3
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  [(S)-[8-[8-[(S)-[(2S)-2-methoxy-2-phenylacetyl]oxy-phenylmethyl]naphthalen-1-yl]oxynaphthalen-1-yl]-phenylmethyl] (2S)-2-methoxy-2-phenylacetate 在 水 作用下， 生成 (S)-[8-[8-[(S)-hydroxy(phenyl)methyl]naphthalen-1-yl]oxynaphthalen-1-yl]-phenylmethanol
  参考文献：
  名称：

  The first synthesis of an optically active molecular bevel gear with only two cogs on each wheel

  摘要：

  Both enantiomers of the molecular bevel gear 1 having only two cogs on each wheel consisting of 8,8'-disubstituted 1,1'-binaphthyl ether were synthesized for the first time. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(97)10848-6
• 作为产物：
  描述：

  8,8'-diformyl-1,1'-binaphthyl ether 生成 [(S)-[8-[8-[(S)-[(2S)-2-methoxy-2-phenylacetyl]oxy-phenylmethyl]naphthalen-1-yl]oxynaphthalen-1-yl]-phenylmethyl] (2S)-2-methoxy-2-phenylacetate
  参考文献：
  名称：

  The first synthesis of an optically active molecular bevel gear with only two cogs on each wheel

  摘要：

  Both enantiomers of the molecular bevel gear 1 having only two cogs on each wheel consisting of 8,8'-disubstituted 1,1'-binaphthyl ether were synthesized for the first time. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(97)10848-6