[La(picrate)3(N-ethyl-2-(2'-((ethyl-phenyl-carbamoyl)-methoxy)-[1,1']binaphthalenyl-2-yloxy)-N-phenyl-acetamide)] | 636566-25-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [La(picrate)3(N-ethyl-2-(2'-((ethyl-phenyl-carbamoyl)-methoxy)-[1,1']binaphthalenyl-2-yloxy)-N-phenyl-acetamide)]
• CAS: 636566-25-1
• 化学式: C₅₈H₄₂LaN₁₁O₂₅
• 分子量: 1431.94
• InChiKey: GCASQSCJENQSIX-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Phenol, 2,4,6-trinitro-, lanthanum(3+) salt 、 N-ethyl-2-(2'-((ethyl-phenyl-carbamoyl)-methoxy)-[1,1']binaphthalenyl-2-yloxy)-N-phenyl-acetamide 以 乙醇 为溶剂， 生成 [La(picrate)3(N-ethyl-2-(2'-((ethyl-phenyl-carbamoyl)-methoxy)-[1,1']binaphthalenyl-2-yloxy)-N-phenyl-acetamide)]
  参考文献：
  名称：

  Synthesis and structural characterization of lanthanide picrate complexes with a new binaphthylamide

  摘要：

  Solid complexes of lanthanide picrates with N-Ethyl-2-{2'-[(ethyl-phenyl-carbamoyl)-methoxy]-[1,1']binaphthalenyl-2-yloxy }-N-phenyl-acetamide (L), [Ln(pic)(3)L] (Ln = La, Th, Y), have been prepared and characterized by elemental analysis, IR and H-1 NMR spectra. The molecular structure of [Tb(pic)(3)L] shows that the Tb(III) ion is nine-coordinated by four oxygen atoms from the L and five from two bidentate and one unidentate picrates. The complex forms a 1D supramolecular structure along z-axis. (C) 2003 Published by Elsevier B.V.

  DOI：

  10.1016/s0022-2860(03)00531-3