2,3-di-p-tolylfumaric acid | 111064-98-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 2,3-di-p-tolylfumaric acid
• 英文别名: di-p-tolyl-fumaric acid；Di-p-tolyl-fumarsaeure；α.β-Di-p-tolyl-aethylen-α.β-dicarbonsaeure；4.4'-Dimethyl-stilben-α.α'-dicarbonsaeure；Di-p-tolyl-maleinsaeure；(E)-2,3-bis(4-methylphenyl)but-2-enedioic acid
• CAS: 111064-98-3
• 化学式: C₁₈H₁₆O₄
• 分子量: 296.323
• InChiKey: LMUXZTJQOXFCFD-FOCLMDBBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  di-p-tolyl-fumaric acid diethyl ester 在 氢氧化钾 作用下， 生成 2,3-di-p-tolylfumaric acid
  参考文献：
  名称：

  Hoch; Choisy, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1959, vol. 248, p. 3314

  摘要：

  DOI：

文献信息

• Electrochemical E-Selective Semireductive Dicarboxylation of Aryl Alkynes with CO2
  作者：Lan Zhao、Wen-Jun Xie、Zheng-Zheng Meng、Hong-Ru Li、Liang-Nian He

  DOI：10.1021/acs.orglett.4c00860

  日期：2024.4.19

  Herein, we report an electrochemical protocol for the dicarboxylation of aryl alkynes using CO2. With a graphite rod as the cathode and Al as the sacrificial anode, a series of valuable butenedioic acids are obtained in moderate to excellent yields with an E/Z ratio up to 50:1. This method features high E-selectivity, high step and atom economy, easy scalability, and a nice substrate scope, which renders

  在此，我们报告了使用 CO 2芳基炔烃二羧化的电化学方案。以石墨棒为阴极，Al为牺牲阳极，以中等至优异的收率获得了一系列有价值的丁烯二酸， E / Z比高达50:1。该方法具有高E选择性、高步骤和原子经济性、易于扩展性和良好的底物范围，这使其在有机合成和材料化学中具有广阔的应用前景。
• POLYESTER COPOLYMER
  申请人：Avantium Knowledge Centre B.V.

  公开号：EP3625283A1

  公开（公告）日：2020-03-25
• Polyester Copolymer
  申请人：Avantium Knowledge Centre B.V.

  公开号：US20210139645A1

  公开（公告）日：2021-05-13

  A polyester copolymer, having a number average molecular weight of equal to or more than 4000 grams/mole and having a glass transition temperature of less than 160° C., containing: (a) in the range from equal to or more than 45 mole % to equal to or less than 50 mole %, based on the total amount of moles of monomer units within the polyester copolymer, of one or more bicyclic diol monomer units, wherein such one or more bicyclic diol monomer units is/are derived from one or more bicyclic diols chosen from the group consisting of isosorbide, isoidide, isomannide, 2,3:4,5-di-O-methylene-galactitol and 2,4:3,5-di-O-methylene-D-mannitol; (b) in the range from equal to or more than 25 mole % to equal to or less than 49.9 mole %, based on the total amount of moles of monomer units within the polyester copolymer, of an oxalate monomer unit; (c) in the range from equal to or more than 0.1 mole % to equal to or less than 25 mole %, based on the total amount of moles of monomer units within the polyester copolymer, of one or more linear C3-C12 dicarboxylate monomer units; and (d) optionally equal to or more than 0 mole % to equal to or less than 5 mole %, based on the total amount of moles of monomer units within the polyester copolymer, of one or more additional monomer units. A process for producing such a polyester copolymer, a composition containing such polyester copolymer, a method for manufacturing an article comprising the use of one or more of such polyester copolymers and an article obtained or obtainable by such a method.
• US4713472A
  申请人：——

  公开号：US4713472A

  公开（公告）日：1987-12-15
• [EN] POLYESTER COPOLYMER<br/>[FR] COPOLYMÈRE DE POLYESTER
  申请人：AVANTIUM KNOWLEDGE CENTRE BV

  公开号：WO2018211132A1

  公开（公告）日：2018-11-22

  A polyester copolymer, having a number average molecular weight of equal to or more than 4000 grams/mole and having a glass transition temperature of less than 160°C, containing: (a) in the range from equal to or more than 45 mole % to equal to or less than 50 mole %, based on the total amount of moles of monomer units within the polyester copolymer, of one or more bicyclic diol monomer units, wherein such one or more bicyclic diol monomer units is/are derived from one or more bicyclic diols chosen from the group consisting of isosorbide, isoidide, isomannide, 2,3:4,5-di-O-methylene-galactitol and 2,4:3,5-di-O-methylene-D- mannitol; (b) in the range from equal to or more than 25 mole % to equal to or less than 49.9 mole %, based on the total amount of moles of monomer units within the polyester copolymer, of an oxalate monomer unit; (c) in the range from equal to or more than 0.1 mole % to equal to or less than 25 mole %, based on the total amount of moles of monomer units within the polyester copolymer, of one or more linear C3-C12 dicarboxylate monomer units; and (d) optionally equal to or more than 0 mole % to equal to or less than 5 mole %, based on the total amount of moles of monomer units within the polyester copolymer, of one or more additional monomer units. A process for producing such a polyester copolymer, a composition containing such polyester copolymer, a method for manufacturing an article comprising the use of one or more of such polyester copolymers and an article obtained or obtainable by such a method.