chloroethyl vinyl ether | 4245-34-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: chloroethyl vinyl ether
• 英文别名: α-chloroethylvinyl ether；(1-chloro-ethoxy)-ethene；(1-chloro-ethyl)-vinyl ether；(1-Chlor-aethyl)-vinyl-aether；1-Chlor-1-vinyloxy-aethan；1-Chloroethyl vinyl ether；1-chloro-1-ethenoxyethane
• CAS: 4245-34-5
• 化学式: C₄H₇ClO
• 分子量: 106.552
• InChiKey: MCHFODQOWYDZEB-UHFFFAOYSA-N

物化性质

• 沸点：
  25 °C(Press: 31 Torr)
• 密度：
  1.0232 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  6
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  chloroethyl vinyl ether 生成 C₄H₇Cl₄O₂P
  参考文献：
  名称：

  Fridland,S.V. et al., Journal of general chemistry of the USSR, 1970, vol. 40, p. 1980 - 1982

  摘要：

  DOI：
• 作为产物：
  描述：

  二乙烯基醚 在 盐酸 作用下， 生成 chloroethyl vinyl ether
  参考文献：
  名称：

  Schostakowskii; Dubrowa, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1958, p. 339,341; engl. Ausg. S. 319, 320

  摘要：

  DOI：

文献信息

• Pyridyl-tetrahydropyrans and process for preparing same
  申请人：Imperial Chemical Industries Limited

  公开号：US04048180A1

  公开（公告）日：1977-09-13

  The present invention deals with intermediate compounds, namely 4-(2'-, 3'- and 4'-pyridyl)-tetrahydropyrans and a process for their preparation. These compounds are prepared by reacting a 2'-haloethyl-3-(pyridyl)propyl ether with an alkali metal amide at -80.degree. C. to 40.degree. C.

  本发明涉及中间化合物，即4-(2'-、3'-和4'-吡啶基)-四氢吡喃及其制备方法。这些化合物是通过将2'-卤乙基-3-(吡啶基)丙基醚与碱金属酰胺在-80摄氏度至40摄氏度下反应而制备的。
• Vinyl ethers, process for their preparation, and their use for the
  申请人：Ciba-Geigy Corporation

  公开号：US04206309A1

  公开（公告）日：1980-06-03

  The present invention relates to new hydantoin vinyl ethers of the formula ##STR1## in which R.sub.1 is hydrogen or an organic radical, R.sub.2 is an alkylene group, and R.sub.3 and R.sub.4 are preferably lower alkyl groups. These compounds are used for the preparation of homopolymers and copolymers, which can used as thickeners, solubilizing agents, binders, thixotropic agents, complexing agents, stabilizers and so forth.

  本发明涉及新的咪唑烷基乙烯醚，其化学式为##STR1##其中R.sub.1是氢或有机基团，R.sub.2是烷基基团，R.sub.3和R.sub.4最好是较低的烷基基团。这些化合物用于制备均聚物和共聚物，可用作增稠剂、增溶剂、粘合剂、流变剂、络合剂、稳定剂等。
• Competition between n,?- and n,?-orbital interactions in chlorinated ethers R-O-chcir 1
  作者：A. A. Bredikhin、V. A. Kirillovich、I. A. Safin、A. N. Vereshchagin

  DOI：10.1007/bf00961034

  日期：1991.11

  Using the AM-1 method, we have studied CH2=CH-O-HClR1 molecules (R1 = H, Me). We have shown that the sc conformation with respect to the C(sp3)-O bond is preferred. We have systematized the Cl-35 NQR data on the degree of manifestation of the generalized anomeric effect in R-OCHClR1 [R = Me, Ph, Vyn, R2C(=O)] molecules. We have established that enhancement of n, pi-conjugation in the R-O fragment leads to weakening of the n, sigma-interaction in the O-C-Cl triad.