[8-[8-(Hydroxymethyl)naphthalen-1-yl]oxynaphthalen-1-yl]methanol | 204583-79-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [8-[8-(Hydroxymethyl)naphthalen-1-yl]oxynaphthalen-1-yl]methanol
• CAS: 204583-79-9
• 化学式: C₂₂H₁₈O₃
• 分子量: 330.383
• InChiKey: YRZKHNWNKJJROQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  49.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  [8-[8-(Hydroxymethyl)naphthalen-1-yl]oxynaphthalen-1-yl]methanol 、 alkaline earth salt of/the/ methylsulfuric acid 以92%的产率得到[8-[8-(Acetyloxymethyl)naphthalen-1-yl]oxynaphthalen-1-yl]methyl acetate
  参考文献：
  名称：

  The first synthesis of an optically active molecular bevel gear with only two cogs on each wheel

  摘要：

  Both enantiomers of the molecular bevel gear 1 having only two cogs on each wheel consisting of 8,8'-disubstituted 1,1'-binaphthyl ether were synthesized for the first time. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(97)10848-6
• 作为产物：
  描述：

  8,8'-diformyl-1,1'-binaphthyl ether 在 lithium aluminium tetrahydride 作用下， 以98%的产率得到[8-[8-(Hydroxymethyl)naphthalen-1-yl]oxynaphthalen-1-yl]methanol
  参考文献：
  名称：

  The first synthesis of an optically active molecular bevel gear with only two cogs on each wheel

  摘要：

  Both enantiomers of the molecular bevel gear 1 having only two cogs on each wheel consisting of 8,8'-disubstituted 1,1'-binaphthyl ether were synthesized for the first time. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(97)10848-6