bis-1,1'-(1,4-dihydronaphthalene) | 71089-50-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: bis-1,1'-(1,4-dihydronaphthalene)
• 英文别名: 1-(1,4-dihydronaphthalen-1-yl)-1,4-dihydronaphthalene
• CAS: 71089-50-4
• 化学式: C₂₀H₁₈
• 分子量: 258.363
• InChiKey: ALSSESLGNUPKNM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.78
• 重原子数：
  20.0
• 可旋转键数：
  1.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  bis(1-naphthyl)sulfide 生成 bis-1,1'-(1,4-dihydronaphthalene)
  参考文献：
  名称：

  FRANCISCO, MANUEL A.;KURS, ARGO;KATRITZKY, ALAN R.;RASALA, DANUTA, J. ORG. CHEM., 53,(1988) N 3, 596-600

  摘要：

  DOI：

文献信息

• A striking solvent effect on the photochemical reaction of naphthalene with 2-(diethylamino)ethanol
  作者：Ayako Ogawa、Shin-Chol Oh、Shin-ichi Satoh、Yasuhiko Shirota

  DOI：10.1039/c39910001195

  日期：——

  Photochemical reaction of naphthalene with 2-(diethylamino)ethanol shows a striking effect of solvent polarity on the reaction course, which is explained in terms of the intermediacy of a geminate radical ion pair in benzene and free radical ions in acetonitrile.

  萘与2-（二乙氨基）乙醇的光化学反应对反应过程显示出显着的溶剂极性影响，这可以通过苯中的双键自由基离子对和乙腈中的自由基离子的中间体来解释。
• The Effect of the Hydrogen Bonding on the Photoinduced Electron Transfer Reaction of a Naphthalene–Triethylamine System in the Presence of Alcohols
  作者：Shin-Choi Oh、Yasuhiko Shirota、Hiroshi Mikawa、Shigekazu Kusabayashi

  DOI：10.1246/cl.1986.2121

  日期：1986.12.5

  The effect of the addition of alcohols on the photoinduced electron transfer reaction of a naphthalene–triethylamine system has been studied. The results show that the addition of alcohol reduces both bimolecular rate constants for the quenching of the naphthalene fluorescence by triethylamine and the quantum yields for the formation of products, in the order of 2-methyl-2-propanol < 2-propanol < ethanol < methanol. These results are explained in terms of hydrogen-bonding interactions between the amine and alcohols, which suppress the electron transfer process.

  研究了添加醇类对萘-三乙胺体系光诱导电子转移反应的影响。结果表明，添加醇类会降低三乙胺淬灭萘荧光的双分子速率常数和生成产物的量子产率，其顺序为 2-甲基-2-丙醇 < 2-丙醇 < 乙醇 < 甲醇。这些结果可以用胺和醇之间的氢键相互作用来解释，这种作用抑制了电子转移过程。
• Photo-induced dimerization of 1-naphthoxide anion
  作者：Tohru Kitamura、Takeshi Imagawa、Mituyosi Kawanisi

  DOI：10.1016/0040-4020(78)80242-7

  日期：1978.1