N-methyl-N-(1-phenylethyl)naphthalen-1-amine | 14393-13-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N-methyl-N-(1-phenylethyl)naphthalen-1-amine
• CAS: 14393-13-6
• 化学式: C₁₉H₁₉N
• 分子量: 261.4
• InChiKey: RJSZXLADHBIOPN-UHFFFAOYSA-N

物化性质

• 沸点：
  402.4±14.0 °C(Predicted)
• 密度：
  1.074±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• OPTICALLY ACTIVE 3-METHYLCYCLOPENTADECANONE AND METHOD FOR PRODUCING INTERMEDIATE THEREOF
  申请人：Takasago International Corporation

  公开号：EP1884509A1

  公开（公告）日：2008-02-06

  Disclosed is a method for producing an optically active 3-methylcyclopentadecan-1-one which is characterized in that 2-cyclopentadecen-1-one is subjected to a 1,4-conjugate addition reaction of a methyl group by using a methylated organic metal in the presence of a copper catalyst, an enol anion scavenger and a specific optically active phosphoramidite for obtaining an optically active 3-methyl-1-cyclopentadecene derivative, and then the thus-obtained 3-methyl-1-cyclopentadecene derivative is subjected to a solvolysis.

  本发明公开了一种生产具有光学活性的 3-甲基环十五烯-1-酮的方法，其特征在于：在铜催化剂存在下，使用甲基化的有机金属，使 2-环十五烯-1-酮与一个甲基发生 1，4-共轭加成反应、烯阴离子清除剂和特定光学活性亚磷酰胺，以获得光学活性 3-甲基-1-环 十五烯衍生物，然后将由此获得的 3-甲基-1-环十五烯衍生物进行溶解。
• Optically Active 3-Methylcyclopentadecanone And Method For Producing Intermediate Thereof
  申请人：Tanaka Shigeru

  公开号：US20090124826A1

  公开（公告）日：2009-05-14

  Disclosed is a method for producing an optically active 3-methylcyclopentadecan-1-one which is characterized in that 2-cyclopentadecen-1-one is subjected to a 1,4-conjugate addition reaction of a methyl group by using a methylated organic metal in the presence of a copper catalyst, an enol anion scavenger and a specific optically active phosphoramidite for obtaining an optically active 3-methyl-1-cyclopentadecene derivative, and then the thus-obtained 3-methyl-1-cyclopentadecene derivative is subjected to a solvolysis.
• US7728177B2
  申请人：——

  公开号：US7728177B2

  公开（公告）日：2010-06-01