[2,4,6-tris(dimethylaminomethyl)phenolato]bis(triphenylphosphine)silver(I) | 616880-27-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [2,4,6-tris(dimethylaminomethyl)phenolato]bis(triphenylphosphine)silver(I)
• CAS: 616880-27-4
• 化学式: C₅₁H₅₆AgN₃OP₂
• 分子量: 896.841
• InChiKey: KWIKSJAZDLLZNT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三苯基膦 、 2,4,6-三(二甲氨基甲基)苯酚 、 silver(l) oxide 以 甲苯 为溶剂， 以66%的产率得到[2,4,6-tris(dimethylaminomethyl)phenolato]bis(triphenylphosphine)silver(I)
  参考文献：
  名称：

  Silver(I) aryloxide–triphenylphosphine complexes. An assessment of their potential as CVD precursors and the structure of [Ag(OC6H4Me-2)(PPh3)3]·2-MeC6H4OH·C6H5Me

  摘要：

  The silver aryloxide-triphenylphoshine complexes [Ag(OR)(PPh3)(2)] (R = C6H2Cl3-2,4,6 (1), C6H4Me-2 (2) or C6H2(CH2NMe2)(3)-2,4,6 (3)) and [Ag(OR)(PPh3)(3)].ROH (R = Ph (4) or C6H4Me-2 (5)) have been prepared and characterised. Complexes 1, 3 and 5 were tested as precursors for the growth of silver films on glass substrates using an aerosol-assisted chemical vapour deposition method. Although films were produced, they were of poor quality compared to those produced from other silver complexes as precursors. A crystal structure determination of 5 as a toluene solvate shows the o-cresolato ligand to be monodentate and together with the triphenylphosphine ligands generates a distorted tetrahedral array around the silver. The additional o-cresol molecule is hydrogen-bonded to the o-cresolato oxygen atom and not directly bonded to silver. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00077-x