{10-(acetyloxy)-1-[5[2,4-cyclohexadienyl]-3-furanyl]-1,3,3a,4b,5,6,6a,7,8,9,10,10a,10b,11,12,12a-hexadecahydro-4b,7,7,10a,12a-pentamethyl-3,5-dioxooxireno[2,3-c]phenanthro[1,2-d]pyran-8-yl}ester acetic acid | 1610828-70-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 萘并吡喃类
• 英文名称: {10-(acetyloxy)-1-[5[2,4-cyclohexadienyl]-3-furanyl]-1,3,3a,4b,5,6,6a,7,8,9,10,10a,10b,11,12,12a-hexadecahydro-4b,7,7,10a,12a-pentamethyl-3,5-dioxooxireno[2,3-c]phenanthro[1,2-d]pyran-8-yl}ester acetic acid
• CAS: 1610828-70-0
• 化学式: C₃₆H₄₄O₉
• 分子量: 620.74
• InChiKey: AQVOAKZYEWGXOC-MSMWBEPZSA-N

反应信息

• 作为产物：
  描述：

  tricarbonyl[1,4-η-5-(7-ketokhivorino)cyclohexa-1,3-diene]iron 在 十二/十四烷基二甲基氧化胺 作用下， 以 甲苯 为溶剂， 反应 1.0h， 生成 {10-(acetyloxy)-1-[5[2,4-cyclohexadienyl]-3-furanyl]-1,3,3a,4b,5,6,6a,7,8,9,10,10a,10b,11,12,12a-hexadecahydro-4b,7,7,10a,12a-pentamethyl-3,5-dioxooxireno[2,3-c]phenanthro[1,2-d]pyran-8-yl}ester acetic acid
  参考文献：
  名称：

  Demetallation of 1,3-diene products obtained from addition of natural products to tricarbonyl(cyclohexadienyl)iron tetrafluoroborate

  摘要：

  The demetallation of adducts obtained from the addition of biologically active natural products to [Fe (1-5-eta-C6H7) (CO)(3)][BF4] using the oxidizing agent, trimethylamine-N-oxide, afford new organic compounds which are otherwise inaccessible by conventional organic techniques. The products of demetallation were characterized using NMR (H-1, C-13), MS and IR spectroscopic measurements. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2013.12.042