| 1621714-41-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1621714-41-7
• 化学式: C₃₆H₃₉NO₆S
• 分子量: 613.775
• InChiKey: XCSQUXKSUPTGHS-KJQSSVQNSA-N

物化性质

• 密度：
  1.23±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

反应信息

• 作为产物：
  描述：

  2,3,4,6-tetra-O-benzyl-1-O-[N-methylthionocarbamoyl]-D-glucopyranose 在 三氟甲磺酸三甲基硅酯 作用下， 以 甲苯 为溶剂， 反应 0.08h， 以60%的产率得到
  参考文献：
  名称：

  Simple synthesis of glycosylthiols and thioglycosides by rearrangement of O-glycosyl thionocarbamates

  摘要：

  The synthesis of thioglycosides has been achieved in a high yielding process employing thionocarbamates prepared from protected reducing sugars and N-alkyl isothiocyanate in the presence of a non-nucleophilic base (K2CO3). In the key step of the synthesis, thionocarbamates were treated with Lewis acid (TMSOTf) to give O,S-rearrangement products that were applied to the synthesis of both anomers of heteroaryl thioglycosides.

  DOI：

  10.1016/j.carres.2014.07.001