bis[(8-bis(p-trifluoromethyl)phenylnaphthylimino)acenaphthene] | 1609159-01-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: bis[(8-bis(p-trifluoromethyl)phenylnaphthylimino)acenaphthene]
• 英文别名: 1-N,2-N-bis[8-[3,5-bis(trifluoromethyl)phenyl]naphthalen-1-yl]acenaphthylene-1,2-diimine
• CAS: 1609159-01-4
• 化学式: C₄₈H₂₄F₁₂N₂
• 分子量: 856.713
• InChiKey: UHCCCXZTZGBYBU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.2
• 重原子数：
  62
• 可旋转键数：
  4
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  24.7
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  乙二醇二甲醚溴化镍 、 bis[(8-bis(p-trifluoromethyl)phenylnaphthylimino)acenaphthene] 以 二氯甲烷 为溶剂， 反应 24.0h， 以14%的产率得到
  参考文献：
  名称：

  Secondary Alkene Insertion and Precision Chain-Walking: A New Route to Semicrystalline “Polyethylene” from α-Olefins by Combining Two Rare Catalytic Events

  摘要：

  While traditional polymerization of linear alpha-olefins (LAOs) typically provides amorphous, low T-g polymers, chain-straightening polymerization represents a route to semicrystalline materials. A series of alpha-diimine nickel catalysts were tested for the polymerization of various LAOs. Although known systems yielded amorphous or low-melting polymers, the "sandwich" alpha-diimines 3-6 yielded semicrystalline "polyethylene" comprised primarily of unbranched repeat units via a combination of uncommon regioselective 2,1-insertion and precision chain-walking events.

  DOI：

  10.1021/ja502130w
• 作为产物：
  描述：

  methyl N-{8-[3,5-bis(trifluoromethyl)phenyl]naphthalen-1-yl}-N-[(pyridin-2-yl)carbonyl]carbamate 在 sodium tetrahydroborate 、 甲酸 、 水 、 potassium hydroxide 作用下， 以 甲醇 、 乙醇 为溶剂， 反应 26.5h， 生成 bis[(8-bis(p-trifluoromethyl)phenylnaphthylimino)acenaphthene]
  参考文献：
  名称：

  Secondary Alkene Insertion and Precision Chain-Walking: A New Route to Semicrystalline “Polyethylene” from α-Olefins by Combining Two Rare Catalytic Events

  摘要：

  While traditional polymerization of linear alpha-olefins (LAOs) typically provides amorphous, low T-g polymers, chain-straightening polymerization represents a route to semicrystalline materials. A series of alpha-diimine nickel catalysts were tested for the polymerization of various LAOs. Although known systems yielded amorphous or low-melting polymers, the "sandwich" alpha-diimines 3-6 yielded semicrystalline "polyethylene" comprised primarily of unbranched repeat units via a combination of uncommon regioselective 2,1-insertion and precision chain-walking events.

  DOI：

  10.1021/ja502130w