(5,6-benzo-2-phenyl-4-ethoxy-4-oxo-1,3,2,4-dioxaboraphosphorinane)2 | 133752-27-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (5,6-benzo-2-phenyl-4-ethoxy-4-oxo-1,3,2,4-dioxaboraphosphorinane)2
• 英文别名: 3,13-diethoxy-1,11-diphenyl-2,10,12,20,21,22-hexaoxa-3,13-diphosphonia-1,11-diboranuidapentacyclo[11.7.1.13,11.04,9.014,19]docosa-4,6,8,14,16,18-hexaene
• CAS: 133752-27-9
• 化学式: C₂₈H₂₈B₂O₈P₂
• 分子量: 576.095
• InChiKey: LJJNCSUPASWTHN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  P-(2-羟基苯基)-膦酸二乙酯 、 2-甲基丙氧基(二苯基)硼烷 以49%的产率得到(5,6-benzo-2-phenyl-4-ethoxy-4-oxo-1,3,2,4-dioxaboraphosphorinane)2
  参考文献：
  名称：

  Borylation of o-Hydroxyphenyl phosphorus derivatives

  摘要：

  The reactions of isobutyl diphenylborate with O,O-diethyl o-hydroxyphenylphosphonate and o-hydroxyphenylphosphine gave 5,6-benzo-2-phenyl-4-ethoxy-4-oxo-1,3,2,4-dioxaboraphosphorinane and o-diphenylboryloxyphenylphosphine, respectively. The borylation only at the alpha-hydroxyalkyl fragments of bis(beta,beta,beta-trichloro-alpha-hydroxyethyl)(o-hydroxyphenyl)phosphine and the conversion of the o-boryloxyphenyl phosphorus derivative to an alpha-boryloxyalkyl derivative upon the action of chloral indicates the greater stability of compounds with the P-C-O-B fragment than that for compounds with the P-C-C-O-B fragment.

  DOI：

  10.1007/bf00965441

文献信息

• BALUEVA, I. S.;NIKONOV, G. N.;VULFSON, S. G.;SARVAROVA, N. N.;ARBUZOV, B.+, IZV. AN CCCP. CEP. XIM.,(1991) N, S. 477-482
  作者：BALUEVA, I. S.、NIKONOV, G. N.、VULFSON, S. G.、SARVAROVA, N. N.、ARBUZOV, B.+

  DOI：——

  日期：——