4-(7-methoxymethoxy-2,2,10b-trimethyl-6-oxo-(4ar,10bc)-4a,5,6,10b-tetrahydro-4H-naphtho[1,2-d][1,3]dioxin-4c-ylmethylene)-2-(4-nitro-2-tetrahydropyran-2-yloxymethyl-phenyl)-4H-oxazol-5-one | 69673-60-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• 英文名称: 4-(7-methoxymethoxy-2,2,10b-trimethyl-6-oxo-(4ar,10bc)-4a,5,6,10b-tetrahydro-4H-naphtho[1,2-d][1,3]dioxin-4c-ylmethylene)-2-(4-nitro-2-tetrahydropyran-2-yloxymethyl-phenyl)-4H-oxazol-5-one
• CAS: 69673-60-5
• 化学式: C₃₃H₃₆N₂O₁₁
• 分子量: 636.656
• InChiKey: MHHDJCJYFOVSEO-IWSBVNNPSA-N

反应信息

• 作为产物：
  描述：

  (4aS,10bS)-7-Methoxymethoxy-2,2,10b-trimethyl-4-[1-piperidin-1-yl-meth-(Z)-ylidene]-4a,10b-dihydro-4H,5H-naphtho[1,2-d][1,3]dioxin-6-one 、 2-(4-nitro-2-tetrahydropyran-2-yloxymethyl-phenyl)-4H-oxazol-5-one 生成 4-(7-methoxymethoxy-2,2,10b-trimethyl-6-oxo-(4ar,10bc)-4a,5,6,10b-tetrahydro-4H-naphtho[1,2-d][1,3]dioxin-4c-ylmethylene)-2-(4-nitro-2-tetrahydropyran-2-yloxymethyl-phenyl)-4H-oxazol-5-one
  参考文献：
  名称：

  Tetracyclines. 9. Total synthesis of dl-terramycin

  摘要：

  DOI：

  10.1021/ja00497a035