[copper(I)(1,10-phenanthroline)(μ-thiocyanate)] | 444022-72-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: [copper(I)(1,10-phenanthroline)(μ-thiocyanate)]
• 英文别名: copper(1+);1,10-phenanthroline;isothiocyanate
• CAS: 444022-72-4
• 化学式: C₁₃H₈CuN₃S
• 分子量: 301.839
• InChiKey: UZQAWDZPYFZLLS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 sodium thiocyanide 、 copper(I) bromide 以 neat (no solvent, solid phase) 为溶剂， 以37.8%的产率得到[copper(I)(1,10-phenanthroline)(μ-thiocyanate)]
  参考文献：
  名称：

  Synthesis, crystal structure, and third-order nonlinear optical properties of a copper(I) one-dimensional coordination polymer

  摘要：

  A copper(I) thiocyanate coordination polymer [Cu(Phen)(mu-NCS)]n (I) (Phen = 1,10-phenan-throline) has been synthesized by the low-temperature solid-state reaction. Single-crystal X-ray analyses reveal that compound I possesses a type of one-dimensional (1D) framework structure. Polymer I was characterized by elemental analyses, IR spectra, and UV-visifele spectra. The third-order nonlinear optical properties were also investigated, and they exhibit good nonlinear absorption and self-defocusing performance with modulus of the hyperpolarizability 4.94 x 10(-30) esu for I in a 6.35 x 10(-4) mol dm(-3) DMF solution.

  DOI：

  10.1134/s1070328410010082

文献信息

• The chemical behaviour of the azido group bonded to copper(I): Synthesis and reactivity of thiothiatriazolato and alkynyl complexes
  作者：Girolamo La Monica、Gianattilio Ardizzoia、Sergio Cenini、Francesca Porta

  DOI：10.1016/0022-328x(84)80531-8

  日期：1984.9