| 1586808-92-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• CAS: 1586808-92-5
• 化学式: C₁₃H₂₁NO₄
• 分子量: 255.314
• InChiKey: WPOIVGLVLWQRRA-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  、 N-甲基苄胺 在 1,1'-双(二苯基膦)二茂铁 、 bis(η3-allyl-μ-chloropalladium(II)) 作用下， 以 甲苯 为溶剂， 反应 4.17h， 生成 tert-butyl 4-[benzyl(methyl)amino]-2,3,4,7-tetrahydro-1H-azepine-1-carboxylate
  参考文献：
  名称：

  Synthesis of new aminocyclitols by selective epoxidation of N-benzyl-N-methyl-2-cyclohepten-1-amine and tert-butyl 4-[benzyl(methyl)amino]-2,3,4,7-tetrahydro-1H-azepine-1-carboxylate

  摘要：

  Synthesis of N-benzyl-N-methyl-2-cyclohepten-1-amine and tert-butyl 4-[benzyl(methyl)amino]-2,3,4,7-tetrahydro-1H-azepine-1-carboxylate from cyclic allyl acetates was performed. The features of stereoselective epoxidation of these substrates were investigated. The subsequent epoxide opening with water led to the formation of new pseudosaccharides, (1RS,2RS,3RS)-3-[benzyl(methyl)amino]-1,2-cycloheptanediol, (1RS,2RS,3SR)-3-[benzyl(methyl)amino]-1,2-cycloheptanediol, and (3RS,4RS,5RS)-3-[benzyl(methyl)amino]-4,5-azepanediol.

  DOI：

  10.1134/s1070428014020183