2,2'-(((1,2-diphenylethane-1,2-diylidene)bis(hydrazine-2,1-diylidene))bis(methaneylylidene))bis(4-bromophenol) | 1367630-82-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 2,2'-(((1,2-diphenylethane-1,2-diylidene)bis(hydrazine-2,1-diylidene))bis(methaneylylidene))bis(4-bromophenol)
• CAS: 1367630-82-7
• 化学式: C₂₈H₂₀Br₂N₄O₂
• 分子量: 604.3
• InChiKey: NDTFIHVEPOYSOR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.97
• 重原子数：
  36.0
• 可旋转键数：
  7.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  89.9
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  苯偶酰二腙 、 5-溴水杨醛 以 甲醇 为溶剂， 反应 6.0h， 以63%的产率得到2,2'-(((1,2-diphenylethane-1,2-diylidene)bis(hydrazine-2,1-diylidene))bis(methaneylylidene))bis(4-bromophenol)
  参考文献：
  名称：

  Synthesis, Crystal Structure, and Luminescent Properties of a Helical Complex [(CuL)_2.5(H₂O)_0.375] (H₂L = Benzil Bis[(5-bromo oxidobenzylidene)hydrazone])

  摘要：

  A new helical copper (II) complex [(CuL)(2.5)(H2O)(0.375)] 1 (H2L = benzil bis[(5-bromo oxidobenzylidene)hydrazone]) was synthesized and characterized by elemental analysis, IR spectra, UV-vis spectra, and single-crystal X-ray diffraction. Complex 1 exhibits a new single-stranded helix with the copper (II) atom having a four-coordination seesaw geometry. The cooperativity of intermolecular C-H center dot center dot center dot pi interactions and C-H center dot center dot center dot O hydrogen bonds links the helices together to form a three-dimensional network structure. The thermogravimetric and luminescent properties in the solid state of complex 1 have been investigated.

  DOI：

  10.1080/15533174.2011.609228