| 1313192-78-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 1313192-78-7
• 化学式: CF₃O₃S*C₇₂H₉₂NO₆P₂Pd
• 分子量: 1384.96
• InChiKey: SQWODAWKKQGMIB-AUNIXXKTSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  PdCl[25,26;27,28-dibridged p-tert-butyl-calix[4]arene bisphosphite-(C6H2(tBu)-2, Me-4)-(C6H2(tBu)2-2,6, Me-4)] 、 silver trifluoromethanesulfonate 、 乙腈 以 氯仿 为溶剂， 以64%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of cationic cyclopalladated complexes derived from p-tert-butyl-calix[4]arene bisphosphite with nitrogen donors

  摘要：

  A series of new cationic cyclopalladated complexes 2-6 have been synthesized from neutral cyclopalladated complex 1 of p-tert-butyl-calix[4] arene bisphosphite with various nitrogen donor ligands (acetonitrile, pyridine, aniline, (R)-(+)-1-phenylethylamine and 4,4'-bipyridine) in presence of Ag(OSO2CF3) as a chloride scavenger. These cationic cyclopalladated complexes have been characterized by NMR spectroscopy. Single crystal X-ray diffraction studies performed on cationic cyclopalladated complexes 3 and 6 in solid state reveal nearly square planar geometry around the metal and distorted cone conformation of the calix[4] arene framework. These cationic cyclopalladated complexes based on hetero ligands having variable steric and electronic properties could be efficient catalysts for important organic transformation reactions. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.01.085