Antimony(3+);2-(oxidomethyl)-2-propylpropane-1,3-diolate

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: Antimony(3+);2-(oxidomethyl)-2-propylpropane-1,3-diolate
• 英文别名: antimony(3+);2-(oxidomethyl)-2-propylpropane-1,3-diolate
• 化学式: C₇H₁₃O₃*Sb
• 分子量: 266.928
• InChiKey: HNTPIODRSPVCNF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.83
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Antimony(3+);2-(oxidomethyl)-2-propylpropane-1,3-diolate 在 重水 作用下， 以 氘代二甲亚砜 为溶剂， 生成 次丁基三甲醇
  参考文献：
  名称：

  Precise Steric Control over 2D versus 3D Self-Assembly of Antimony(III) Alkoxide Cages through Strong Secondary Bonding Interactions

  摘要：

  Antimony(III) alkoxide cages were designed as building blocks for predictable supramolecular self-assembly. Supramolecular synthons featuring two Sb...O secondary bonding interactions (SBIs), each SBI stronger than 30 kJ/mol, were used to drive the formation of the supramolecular architectures. Judicious choice of pendant groups provided predictable control over the formation of self-assembled 3D columnar helices, which crystallized with hollow morphologies, or a self-assembled 2D bilayer. The Sb...O stretching frequency provides a spectroscopic signature of Sb...O SBI formation.

  DOI：

  10.1021/acs.inorgchem.7b01049
• 作为产物：
  描述：

  次丁基三甲醇 、 antimony(III) tert-butoxide 以 四氢呋喃 为溶剂， 以70.4%的产率得到Antimony(3+);2-(oxidomethyl)-2-propylpropane-1,3-diolate
  参考文献：
  名称：

  Precise Steric Control over 2D versus 3D Self-Assembly of Antimony(III) Alkoxide Cages through Strong Secondary Bonding Interactions

  摘要：

  Antimony(III) alkoxide cages were designed as building blocks for predictable supramolecular self-assembly. Supramolecular synthons featuring two Sb...O secondary bonding interactions (SBIs), each SBI stronger than 30 kJ/mol, were used to drive the formation of the supramolecular architectures. Judicious choice of pendant groups provided predictable control over the formation of self-assembled 3D columnar helices, which crystallized with hollow morphologies, or a self-assembled 2D bilayer. The Sb...O stretching frequency provides a spectroscopic signature of Sb...O SBI formation.

  DOI：

  10.1021/acs.inorgchem.7b01049

文献信息

• Precise Steric Control over 2D versus 3D Self-Assembly of Antimony(III) Alkoxide Cages through Strong Secondary Bonding Interactions
  作者：Shiva Moaven、Jingze Yu、Jason Yasin、Daniel K. Unruh、Anthony F. Cozzolino

  DOI：10.1021/acs.inorgchem.7b01049

  日期：2017.7.17

  Antimony(III) alkoxide cages were designed as building blocks for predictable supramolecular self-assembly. Supramolecular synthons featuring two Sb...O secondary bonding interactions (SBIs), each SBI stronger than 30 kJ/mol, were used to drive the formation of the supramolecular architectures. Judicious choice of pendant groups provided predictable control over the formation of self-assembled 3D columnar helices, which crystallized with hollow morphologies, or a self-assembled 2D bilayer. The Sb...O stretching frequency provides a spectroscopic signature of Sb...O SBI formation.