4-(Naphthalen-2-yloxy)-2,6-dioxa-14,17,20-triaza-tricyclo[20.4.0.0^7,12]hexacosa-1(26),7(12),8,10,22,24-hexaene-14,17,20-tricarboxylic acid tri-tert-butyl ester | 209161-72-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 4-(Naphthalen-2-yloxy)-2,6-dioxa-14,17,20-triaza-tricyclo[20.4.0.0^7,12]hexacosa-1(26),7(12),8,10,22,24-hexaene-14,17,20-tricarboxylic acid tri-tert-butyl ester
• CAS: 209161-72-8
• 化学式: C₄₆H₅₉N₃O₉
• 分子量: 797.989
• InChiKey: XNMVYQNFROYEOX-UHFFFAOYSA-N

物化性质

• 沸点：
  839.852±65.00 °C(Press: 760.00 Torr)(predicted)
• 密度：
  1.141±0.06 g/cm3(Temp: 25 °C; Press: 760 Torr)(predicted)

反应信息

• 作为反应物：
  描述：

  4-(Naphthalen-2-yloxy)-2,6-dioxa-14,17,20-triaza-tricyclo[20.4.0.0^7,12]hexacosa-1(26),7(12),8,10,22,24-hexaene-14,17,20-tricarboxylic acid tri-tert-butyl ester 在 三氟乙酸 作用下， 以 二氯甲烷 为溶剂， 反应 1.0h， 生成 4-(Naphthalen-2-yloxy)-2,6-dioxa-14,17,20-triaza-tricyclo[20.4.0.0^7,12]hexacosa-1(26),7(12),8,10,22,24-hexaene
  参考文献：
  名称：

  High-throughput synthesis and direct screening for the discovery of novel hydrolytic metal complexes

  摘要：

  A 'combinatorial catalysis' strategy was utilized to both rapidly synthesize organometallic complexes and to screen them for catalytic activity in chemical reactions. The application of this strategy has yielded several metal-complexes that catalyze the hydrolysis of carboxylic acid esters efficiently. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0960-894x(98)00199-1
• 作为产物：
  描述：

  二碳酸二叔丁酯 在 sodium hydride 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 13.0h， 生成 4-(Naphthalen-2-yloxy)-2,6-dioxa-14,17,20-triaza-tricyclo[20.4.0.0^7,12]hexacosa-1(26),7(12),8,10,22,24-hexaene-14,17,20-tricarboxylic acid tri-tert-butyl ester
  参考文献：
  名称：

  High-throughput synthesis and direct screening for the discovery of novel hydrolytic metal complexes

  摘要：

  A 'combinatorial catalysis' strategy was utilized to both rapidly synthesize organometallic complexes and to screen them for catalytic activity in chemical reactions. The application of this strategy has yielded several metal-complexes that catalyze the hydrolysis of carboxylic acid esters efficiently. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0960-894x(98)00199-1