bis-(2-methyl-1-naphthoyl)phenylphosphine oxide | 104890-07-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: bis-(2-methyl-1-naphthoyl)phenylphosphine oxide
• 英文别名: [(2-Methylnaphthalene-1-carbonyl)-phenylphosphoryl]-(2-methylnaphthalen-1-yl)methanone
• CAS: 104890-07-5
• 化学式: C₃₀H₂₃O₃P
• 分子量: 462.485
• InChiKey: VWGHOMFQYUCRSK-UHFFFAOYSA-N

物化性质

• 沸点：
  679.3±58.0 °C(Predicted)
• 密度：
  1.28±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  34
• 可旋转键数：
  5
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  51.2
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• [EN] DENTAL COMPOSITION CONTAINING POLYOXOMETALATES, PROCESS OF PRODUCTION AND USE THEREOF<br/>[FR] COMPOSITION DENTAIRE CONTENANT DES POLYOXOMÉTALATES, PROCÉDÉS DE PRODUCTION ET D'UTILISATION DE LADITE COMPOSITION
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2015034977A1

  公开（公告）日：2015-03-12

  The invention relates to a curable composition for dental use comprising polyoxymetalates and/or derivatives thereof in an amount of at least about 5 wt.-% with respect to the weight of the composition.

  该发明涉及一种可治疗的牙科用组合物，其包括聚氧金属酸盐和/或其衍生物，其在组合物的重量上占至少约5重量百分比。
• [EN] DENTAL COMPOSITION AND USE THEREOF<br/>[FR] COMPOSITION DENTAIRE ET SON UTILISATION
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2015126862A1

  公开（公告）日：2015-08-27

  The invention relates to a dental composition comprising polymerizable monomer (1), initiator component(s), filler component(s) in an amount of more than about 20 wt.-%, wt.-% with respect to the whole weight of the composition, the polymerizable monomer (1) being characterized as follows: having exactly two (meth)acrylate reactive moieties, having an unsymmetrical backbone as linkage between the (meth)acrylate reactive moieties, the two (meth)acrylate reactive moieties being attached onto the unsymmetrical monomer backbone as alkyl esters, the unsymmetrical backbone comprising one aromatic moiety of the phenolic type, the polymerizable monomer (1) not containing an acidic moiety, other atoms than carbon, hydrogen, and oxygen, bisphenol moieties. The invention also relates to the use of the dental composition as or for producing a dental filling material, crown and bridge material, inlay, onlay, veneer or dental mill blank.

  该发明涉及一种牙科组合物，包括可聚合单体（1），引发剂成分，填料成分，其含量超过整个组合物重量的20重量％，可聚合单体（1）的特征如下：具有正好两个（甲基）丙烯酸酯反应基团，具有非对称的骨架作为（甲基）丙烯酸酯反应基团之间的连接，两个（甲基）丙烯酸酯反应基团附着在非对称单体骨架上作为烷基酯，非对称骨架包括酚型芳香基团，可聚合单体（1）不含有酸性基团，除碳、氢和氧之外的其他原子，双酚基团。该发明还涉及将该牙科组合物用作或用于生产牙科充填材料，牙冠和桥梁材料，嵌体，瓷贴面或牙科铣削坯料。
• [EN] ADHESIVE BONDING COMPOSITION AND USE THEREOF<br/>[FR] COMPOSITION DE LIAISON ADHÉSIVE ET SON UTILISATION
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2015126865A1

  公开（公告）日：2015-08-27

  An adhesive dental composition comprising apolymerizable monomer (1), a polymerizable monomer (2) comprising an acidic moiety,initiator component(s), filler component(s) in an amount of less than about 15 wt.-%, wt.-% with respect to the whole weight of the composition, the polymerizable monomer (1) being characterized as follows: having exactly two (meth)acrylate reactive moieties, having an unsymmetrical backbone as linkage between the (meth)acrylate reactive moieties, the two (meth)acrylate reactive moieties being attached onto the unsymmetrical monomer backbone as alkyl esters, the unsymmetrical backbone comprising one aromatic moiety of the phenolic type, the polymerizable monomer (1) not containing an acidic moiety, other atoms than carbon, hydrogen, and oxygen, bisphenol moieties. The invention also relates to the use of the adhesive dental composition as dental adhesive, sealant, cement or for bonding or cementing a material to the surface of hard dental tissue.

  一种粘合剂牙科组合物，包括可聚合单体（1）、含有酸性基团的可聚合单体（2）、引发剂组分、填料组分，其含量不超过整个组合物重量的约15重量％，其中可聚合单体（1）具有以下特征：具有正好两个（甲基）丙烯酸酯反应基团，具有不对称的骨架作为连接（甲基）丙烯酸酯反应基团的链，两个（甲基）丙烯酸酯反应基团附着在不对称单体骨架上作为烷基酯，不对称骨架包括酚类的一个芳香基团，可聚合单体（1）不含有酸性基团、除碳、氢和氧之外的其他原子、双酚基团。该发明还涉及将该粘合剂牙科组合物用作牙科粘合剂、密封剂、水泥或用于将材料粘合或水泥到硬质牙齿表面的用途。
• Curable resin composition, molded product, and process for producing the same
  申请人：Yamauchi Shintaro

  公开号：US20090008834A1

  公开（公告）日：2009-01-08

  By heating, allowing to stand at normal temperature, or irradiating in the presence of a photo-polymerization initiator, a curable resin composition which contains (A) a resin material having a radical polymerizable unsaturated group and an epoxy group, (C) a radical polymerization initiator, (D) an amine compound and/or a mercaptan compound containing one or more of active hydrogen in one molecule, and (E) a compound, which is an adduct in which the (D) amine compound and/or a mercaptan compound, is reacted with the radical polymerizable unsaturated group of the (A) resin material, thereby a cured product can be obtained.

  通过加热、在常温下静置或在存在光聚合引发剂的情况下辐照，可以获得可固化树脂组合物，该组合物包含（A）具有自由基聚合不饱和基团和环氧基的树脂材料，（C）自由基聚合引发剂，（D）含有一个或多个活性氢的胺化合物和/或巯基化合物，以及（E）化合物，该化合物是（D）胺化合物和/或巯基化合物与（A）树脂材料的自由基聚合不饱和基团反应形成的加合物，从而可以获得固化产品。
• CURABLE RESIN COMPOSITION, SHAPED ARTICLE AND METHOD FOR PRODUCING SAME
  申请人：SHOWA HIGHPOLYMER CO., LTD.

  公开号：EP1785440A1

  公开（公告）日：2007-05-16

  By heating, allowing to stand at normal temperature, or irradiating in the presence of a photo-polymerization initiator, a curable resin composition which contains (A) a resin material having a radical polymerizable unsaturated group and an epoxy group, (C) a radical polymerization initiator, (D) an amine compound and/or a mercaptan compound containing one or more of active hydrogen in one molecule, and (E) a compound, which is an adduct in which the (D) amine compound and/or a mercaptan compound, is reacted with the radical polymerizable unsaturated group of the (A) resin material, thereby a cured product can be obtained.

  通过加热、在常温下静置或在有光聚合引发剂存在的情况下辐照可固化树脂组合物，该组合物包含 (A) 具有可自由基聚合的不饱和基团和环氧基团的树脂材料，(C) 自由基聚合引发剂、(D) 在一个分子中含有一个或多个活性氢的胺化合物和/或硫醇化合物，以及 (E) 一种化合物，该化合物是(D)胺化合物和/或硫醇化合物与(A)树脂材料的可自由基聚合的不饱和基团反应的加合物，从而可获得固化产品。