{RuBr2(CS)(Me2SO)2} | 134000-99-0

• 分子结构分类: 有机化合物 - 有机硫化合物 - 磺酰类
• 英文名称: {RuBr2(CS)(Me2SO)2}
• CAS: 134000-99-0
• 化学式: C₅H₁₂Br₂O₂RuS₃
• 分子量: 461.225
• InChiKey: NLMLJROJFTZXMN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.33
• 重原子数：
  13.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  34.14
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  二硫化碳 、 RuBr2(DMSO)3 以 甲醇 为溶剂， 以65%的产率得到{RuBr2(CS)(Me2SO)2}
  参考文献：
  名称：

  Reactivity and catalytic activity of [RuBr2(Me2SO)3]

  摘要：

  [RuBr2(Me2SO)3] has been used as precursor for the synthesis of many ruthenium(II) complexes containing bromide ion and other ligands. The complexes, thus synthesised are: [RuBr2L4] (L = PPh3, L2 = phen or bpy); [RuBr2(Me2SO)2L2] (L = py, AsPh3; L2 = phen, bpy or o-phenylenediamine); [RuBr2(CS)(PPh3)3]; [RuBr2(CS)(Me2SO)2]; [RuBr2(CS)(AsPh3)2(Me2SO)] and [RuBr(C2O4H)(Me2SO)2]. These compounds have been characterised with the help of analytical data and various physical methods. [RuBr2(Me2SO)3] has been used as a catalyst for the oxidation of PPh3 by molecular oxygen.

  DOI：

  10.1016/s0020-1693(00)85367-0