24-Methyl-2,11-dioxa-23,26-diazahexacyclo[26.8.0.04,9.012,21.015,20.029,34]hexatriaconta-1(28),4,6,8,12(21),13,15,17,19,29,31,33,35-tridecaene | 1428631-43-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 24-Methyl-2,11-dioxa-23,26-diazahexacyclo[26.8.0.04,9.012,21.015,20.029,34]hexatriaconta-1(28),4,6,8,12(21),13,15,17,19,29,31,33,35-tridecaene
• 英文别名: 24-methyl-2,11-dioxa-23,26-diazahexacyclo[26.8.0.04,9.012,21.015,20.029,34]hexatriaconta-1(28),4,6,8,12(21),13,15,17,19,29,31,33,35-tridecaene
• CAS: 1428631-43-9
• 化学式: C₃₃H₃₂N₂O₂
• 分子量: 488.629
• InChiKey: XEEVTTNQGGLFDV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  37
• 可旋转键数：
  0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  42.5
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  aluminum (III) chloride 、 24-Methyl-2,11-dioxa-23,26-diazahexacyclo[26.8.0.04,9.012,21.015,20.029,34]hexatriaconta-1(28),4,6,8,12(21),13,15,17,19,29,31,33,35-tridecaene 反应 1.0h， 以71%的产率得到
  参考文献：
  名称：

  A highly sensitive and selective off–on fluorescent chemosensor for Al3+ based on naphthalene derivative

  摘要：

  A new dialdehyde (D) containing two emissive naphthalene and its [1+1] macrocycle with 1,2-diaminopropane were synthesized and characterized. The macrocycle was studied by H-1 NMR, C-13 NMR, COSY, HSQC, DEPT, mass spectrometry and microanalysis. The influence of metal cations such as Na+, K+, Cs+, Mg2+, Ba2+, Al3+, Pb2+, Cr3+, Mn2+, Fe3+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Hg2+ and Ag+ on the photophysical properties of the macrocyclic system in DMF and DMF/H2O (9:1, v/v) mixture was investigated by means of emission spectrophotometry. The macrocycle L was found to be as an effective fluorescent sensor for Al3+ ions. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2013.01.009
• 作为产物：
  描述：

  1,2-二(溴甲基)苯 在 potassium carbonate 作用下， 以 甲醇 、 乙腈 为溶剂， 反应 96.08h， 生成 24-Methyl-2,11-dioxa-23,26-diazahexacyclo[26.8.0.04,9.012,21.015,20.029,34]hexatriaconta-1(28),4,6,8,12(21),13,15,17,19,29,31,33,35-tridecaene
  参考文献：
  名称：

  A highly sensitive and selective off–on fluorescent chemosensor for Al3+ based on naphthalene derivative

  摘要：

  A new dialdehyde (D) containing two emissive naphthalene and its [1+1] macrocycle with 1,2-diaminopropane were synthesized and characterized. The macrocycle was studied by H-1 NMR, C-13 NMR, COSY, HSQC, DEPT, mass spectrometry and microanalysis. The influence of metal cations such as Na+, K+, Cs+, Mg2+, Ba2+, Al3+, Pb2+, Cr3+, Mn2+, Fe3+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Hg2+ and Ag+ on the photophysical properties of the macrocyclic system in DMF and DMF/H2O (9:1, v/v) mixture was investigated by means of emission spectrophotometry. The macrocycle L was found to be as an effective fluorescent sensor for Al3+ ions. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2013.01.009

文献信息

• A highly sensitive and selective off–on fluorescent chemosensor for Al3+ based on naphthalene derivative
  作者：Reza Azadbakht、Javad Khanabadi

  DOI：10.1016/j.inoche.2013.01.009

  日期：2013.4

  A new dialdehyde (D) containing two emissive naphthalene and its [1+1] macrocycle with 1,2-diaminopropane were synthesized and characterized. The macrocycle was studied by H-1 NMR, C-13 NMR, COSY, HSQC, DEPT, mass spectrometry and microanalysis. The influence of metal cations such as Na+, K+, Cs+, Mg2+, Ba2+, Al3+, Pb2+, Cr3+, Mn2+, Fe3+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Hg2+ and Ag+ on the photophysical properties of the macrocyclic system in DMF and DMF/H2O (9:1, v/v) mixture was investigated by means of emission spectrophotometry. The macrocycle L was found to be as an effective fluorescent sensor for Al3+ ions. (C) 2013 Elsevier B.V. All rights reserved.