tributyl-[1]naphthyl-silane | 1521-10-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: tributyl-[1]naphthyl-silane
• 英文别名: Tributyl-[1]naphthyl-silan；tributyl(naphthalen-1-yl)silane
• CAS: 1521-10-4
• 化学式: C₂₂H₃₄Si
• 分子量: 326.597
• InChiKey: IYEABKSOIOYKPO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  23.0
• 可旋转键数：
  10.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  1-萘基溴化镁, 0.5M IN METHF 在 四氯化硅 作用下， 生成 tributyl-[1]naphthyl-silane
  参考文献：
  名称：

  Sanin, Zhurnal Obshchei Khimii, 1957, vol. 27, p. 1286,1287;engl.Ausg.S.1371

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 28, page 86 - 90
  作者：

  DOI：——

  日期：——
• Petrov, A. D.; Chugunov, V. S., Doklady Akademii Nauk SSSR, 1950, vol. 73, p. 323 - 326
  作者：Petrov, A. D.、Chugunov, V. S.

  DOI：——

  日期：——
• Adaptive Mollifiers for High Resolution Recovery of Piecewise Smooth Data from its Spectral Information
  作者：Eitan Tadmor、Jared Tanner

  DOI：10.1007/s102080010019

  日期：2002.1

  We discuss the reconstruction of piecewise smooth data from its (pseudo-) spectral information. Spectral projections enjoy superior resolution provided the data is globally smooth, while the presence of jump discontinuities is responsible for spurious O(1) Gibbs oscillations in the neighborhood of edges and an overall deterioration of the unacceptable first-order convergence in rate. The purpose is to regain the superior accuracy in the piecewise smooth case, and this is achieved by mollification.Here we utilize a modified version of the two-parameter family of spectral mollifiers introduced by Gottlieb and Tadmor [GoTa85]. The ubiquitous one-parameter, finite-order mollifiers are based on dilation. In contrast, our mollifiers achieve their high resolution by an intricate process of high-order cancellation. To this end, we first implement a localization step using an edge detection procedure [GeTa00a, b]. The accurate recovery of piecewise smooth data is then carried out in the direction of smoothness away from the edges, and adaptivity is responsible for the high resolution. The resulting adaptive mollifier greatly accelerates the convergence rate, recovering piecewise analytic data within exponential accuracy while removing the spurious oscillations that remained in [GoTa85]. Thus, these adaptive mollifiers offer a robust, general-purpose "black box" procedure for accurate post-processing of piecewise smooth data.
• BOUDIN A.; CERVEAU G.; CHUIT C.; CORRIU J. P.; REYE C., ANGEW. CHEM., 98,(1986) N 5, 472-473
  作者：BOUDIN A.、 CERVEAU G.、 CHUIT C.、 CORRIU J. P.、 REYE C.

  DOI：——

  日期：——