1,2-C6H4[C6H5CH(O)C(C6H5)N]2Cu | 74734-54-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1,2-C6H4[C6H5CH(O)C(C6H5)N]2Cu
• CAS: 74734-54-6
• 化学式: C₃₄H₂₆CuN₂O₂
• 分子量: 558.139
• InChiKey: KWAHRVREMGNIDH-RIXYRUQFSA-N

反应信息

• 作为产物：
  描述：

  dibenzoinlidene-o-phenylene diamine 、 copper dichloride 在 NH₃ 作用下， 以 乙醇 为溶剂， 生成 1,2-C6H4[C6H5CH(O)C(C6H5)N]2Cu
  参考文献：
  名称：

  Mahapatra, Bipin B.; Dash, S. S.; Pujari, S. K., Journal of the Indian Chemical Society, 1980, vol. 57, p. 96 - 97

  摘要：

  DOI：

文献信息

• Complexes of cobalt(II), nickel(II) and copper(II) with ortho- and para-phenylenediamine derivatives
  作者：Issam J. Sallomi、Amera J. Shaheen

  DOI：10.1016/s0277-5387(97)00400-2

  日期：1998.1

  Cobalt(II), nickel(II) and copper(II) complexes with BOP-H-2 (dibenzoinlidene-o-phenylenediamine) and BPP-H-2 (dibenzoinlidene-p-phenylenediamine) of general formulae [M(H2L)X-2], [M-2(H2L)(2)X-4], [M(L)] and [M-2(L)(2)] (where M = Co, Ni, Cu; X = Cl or NO3; H2L and L are the neutral and dibasic forms of the ligands) have been prepared by the reaction of the corresponding metal salts with the two ligands in neutral and basic media. The complexes were characterised by elemental analysis, electrical conductance, magnetic susceptibility and spectral measurements. The studies revealed two different actions of the ligands, neutral tetradentate in neutral medium giving hexacoordinated metal atoms with octahedral geometry and dibasic tetradentate in alkaline solution giving tetrahedral and square planar structures. (C) 1998 Elsevier Science Ltd. All rights reserved.