| 1613314-78-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 1613314-78-5
• 化学式: C₁₈H₂₃N₅NiO
• 分子量: 384.104
• InChiKey: ZVLLHMGKBKFGNG-ZWXFCGGNSA-M

反应信息

• 作为产物：
  描述：

  sodium azide 、 nickel(II) perchlorate hexahydrate 、 2-(1-(2-(diethylamino)ethylimino)ethyl)naphthalen-1-ol 以 甲醇 为溶剂， 反应 2.0h， 以65%的产率得到
  参考文献：
  名称：

  Synthesis, characterization and DFT study of nickel(II) complexes of a N2O donor Schiff base with different pseudo-halides: Formation of supra-molecular architectures by C–H⋯π interactions

  摘要：

  Four new mono-nuclear square planar nickel(II) complexes [Ni(L)(N-3)] (1), [Ni(L)(NCO)] (2), [Ni(L)(NCS)] (3) and [Ni(L)(NCSe)] (4), where HL = 2-(1-(2-(diethylamino)ethylimino)ethyl)naphthalen-1-ol, have been synthesized and characterized by elemental analysis, IR, UV-Vis, fluorescence spectroscopy and single crystal X-ray diffraction studies. The ligand is so designed that there is no possibility of hydrogen bonding interactions in all the four complexes. However, the C-H center dot center dot center dot pi interactions lead to the formation of one-dimensional chain in complex 2 and two-dimensional sheets in the other three complexes. The geometries of all complexes are optimized in the singlet ground states by DFT calculation. Electronic spectra of the complexes are explained using TD DFT calculation. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2014.03.061