1-亚硝基-4-(哌啶-1-基)萘-2-醇 | 149140-04-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 1-亚硝基-4-(哌啶-1-基)萘-2-醇
• 英文名称: 4-(1-Piperidinyl)-1,2-naphthalenedione 1-oxime
• 英文别名: 1-nitroso-4-piperidin-1-ylnaphthalen-2-ol
• CAS: 149140-04-5
• 化学式: C₁₅H₁₆N₂O₂
• 分子量: 256.304
• InChiKey: MGWHWNMLDIOYAC-UHFFFAOYSA-N

物化性质

• 沸点：
  502.7±45.0 °C(Predicted)
• 密度：
  1.29±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  19
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  52.9
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,3,3-trimethyl-2-methylene-5-(trifluoromethyl)indolenine 、 1-亚硝基-4-(哌啶-1-基)萘-2-醇 以 甲醇 为溶剂， 以3%的产率得到
  参考文献：
  名称：

  Red Colouring Photochromic 6′-Substituted Spiroindolinon Aphth[2,1-b][1,4]Oxazines

  摘要：

  Electron donating/withdrawing substituents and electronegative centres have been successfully employed in substantially widening the range of photo-generated colours available in the spiroindolinonaphthoxazine class of photochromic materials.

  DOI：

  10.1080/10587259408037780
• 作为产物：
  描述：

  sodium 1,2-naphthoquinone-4-sulfonate 在 盐酸羟胺 作用下， 以 乙醇 、 水 为溶剂， 生成 1-亚硝基-4-(哌啶-1-基)萘-2-醇
  参考文献：
  名称：

  Red Colouring Photochromic 6′-Substituted Spiroindolinon Aphth[2,1-b][1,4]Oxazines

  摘要：

  Electron donating/withdrawing substituents and electronegative centres have been successfully employed in substantially widening the range of photo-generated colours available in the spiroindolinonaphthoxazine class of photochromic materials.

  DOI：

  10.1080/10587259408037780

文献信息

• Synthesis, characterization and photochromic studies in film of heterocycle-containing spirooxazines
  作者：Ting-feng Tan、Pei-li Chen、Hua-ming Huang、Ji-ben Meng

  DOI：10.1016/j.tet.2005.06.057

  日期：2005.8

  A series of novel heterocycle-containing spirooxazines have been designed and synthesized, and their photochromic properties were investigated under flash photolysis and continuous irradiation in particular regard to the fatigue resistance, the lifetime of the colored merocyanine form in various solutions and polymers. Especially, the characteristics of two UV-sensitive spirooxazines dispersed polymethylmethacrylate thin-films were extensively studied. Detailed studies showed that general significant shifts in the lambda(max) of the absorption spectra of the open forms, interesting fatigue resistances and emission fluorescene properties were observed. (c) 2005 Elsevier Ltd. All rights reserved.