9-N,9-N,28-N,28-N-tetrabutyl-6,31-dioxa-3,21-diazanonacyclo[22.11.1.02,22.04,20.05,13.07,12.014,19.025,30.032,36]hexatriaconta-1(36),2(22),3,5(13),7(12),8,10,14,16,18,20,23,25(30),26,28,32,34-heptadecaene-9,28-diamine | 1187036-73-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• 英文名称: 9-N,9-N,28-N,28-N-tetrabutyl-6,31-dioxa-3,21-diazanonacyclo[22.11.1.02,22.04,20.05,13.07,12.014,19.025,30.032,36]hexatriaconta-1(36),2(22),3,5(13),7(12),8,10,14,16,18,20,23,25(30),26,28,32,34-heptadecaene-9,28-diamine
• CAS: 1187036-73-2
• 化学式: C₄₈H₅₀N₄O₂
• 分子量: 714.951
• InChiKey: OYDCABJHBIBUCV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.4
• 重原子数：
  54
• 可旋转键数：
  14
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  54.6
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  9-dibutylamino-benzo[b]naphtho[1,2-d]furan-5,6-dione 在 吡啶 、 盐酸 、 盐酸羟胺 、 tin(ll) chloride 作用下， 以 乙醇 、 水 为溶剂， 反应 21.0h， 生成 9-N,9-N,28-N,28-N-tetrabutyl-6,31-dioxa-3,21-diazanonacyclo[22.11.1.02,22.04,20.05,13.07,12.014,19.025,30.032,36]hexatriaconta-1(36),2(22),3,5(13),7(12),8,10,14,16,18,20,23,25(30),26,28,32,34-heptadecaene-9,28-diamine 、 15-N,15-N,28-N,28-N-tetrabutyl-18,31-dioxa-3,21-diazanonacyclo[22.11.1.02,22.04,20.05,10.011,19.012,17.025,30.032,36]hexatriaconta-1(36),2(22),3,5,7,9,11(19),12(17),13,15,20,23,25(30),26,28,32,34-heptadecaene-15,28-diamine
  参考文献：
  名称：

  Photophysical properties and photostability of novel symmetric polycyclicphenazine-type fluorescent dyes and the dye-doped films

  摘要：

  Novel symmetric polycyclicphenazine-type fluorescent dyes have been synthesized and characterized in solution and in polymer films. The dyes exhibited two strong absorption bands at around 365-428 nm and 519-567 nm and an intense fluorescence band at around 560-600 nm (Phi = 0.70-0.87) in 1,4-dioxane. The dye-doped polymer films showed excellent wavelength conversion function that efficiently convert ultraviolet and yellow lights into red light (Phi = 0.61-0.92). Moreover, the photostability of the dye-doped PS, PMMA, and PLA films has been investigated. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2011.11.010