RuBr2(1,10-phenanthroline)2(DMSO)2 | 118541-62-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: RuBr2(1,10-phenanthroline)2(DMSO)2
• CAS: 118541-62-1
• 化学式: C₁₆H₂₀Br₂N₂O₂RuS₂
• 分子量: 597.357
• InChiKey: DLJSXONAHZJBMU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 RuBr2(DMSO)3 以 甲醇 为溶剂， 以68%的产率得到RuBr2(1,10-phenanthroline)2(DMSO)2
  参考文献：
  名称：

  Reactivity and catalytic activity of [RuBr2(Me2SO)3]

  摘要：

  [RuBr2(Me2SO)3] has been used as precursor for the synthesis of many ruthenium(II) complexes containing bromide ion and other ligands. The complexes, thus synthesised are: [RuBr2L4] (L = PPh3, L2 = phen or bpy); [RuBr2(Me2SO)2L2] (L = py, AsPh3; L2 = phen, bpy or o-phenylenediamine); [RuBr2(CS)(PPh3)3]; [RuBr2(CS)(Me2SO)2]; [RuBr2(CS)(AsPh3)2(Me2SO)] and [RuBr(C2O4H)(Me2SO)2]. These compounds have been characterised with the help of analytical data and various physical methods. [RuBr2(Me2SO)3] has been used as a catalyst for the oxidation of PPh3 by molecular oxygen.

  DOI：

  10.1016/s0020-1693(00)85367-0

文献信息

• Complexes of ruthenium(III) and -(II) with dimethylsulphoxide—II. [RuBr3(Me2SO)3] and [RuBr2(Me2SO)3]: Versatile starting materials for the syntheses of ruthenium bromo complexes
  作者：Uma Charan Sarma、Raj K. Poddar

  DOI：10.1016/s0277-5387(00)80405-2

  日期：1988.1