1,1-dideuterio-2,2,2-trifluoro-1-iodo-ethane | 558-60-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: 1,1-dideuterio-2,2,2-trifluoro-1-iodo-ethane
• 英文别名: 1,1-Dideuterio-2,2,2-trifluor-1-jod-aethan
• CAS: 558-60-1
• 化学式: C₂H₂F₃I
• 分子量: 211.922
• InChiKey: RKOUFQLNMRAACI-DICFDUPASA-N

反应信息

• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 sodium iodide 、 二乙二醇 作用下， 生成 1,1-dideuterio-2,2,2-trifluoro-1-iodo-ethane
  参考文献：
  名称：

  Vibrational Spectra of CF₂ = CHD and CF₂ = CD₂

  摘要：

  A method has been devised to prepare CF2 = CD2 and CF2 = CHD. The infrared spectra of the gaseous compounds and the Raman spectra of the liquids have been determined. The observed frequencies have been assigned to the fundamental modes of vibration and to overtones and combinations. The torsional frequency has been estimated as ca 720 and ca 520 cm—1 in CF2 = CH2 and CF2 = CD2, respectively. The overtone of the torsional frequency interacts with the CH2 or the CD2 deformation fundamental and this is the cause of the anomalous results with the product rule.

  DOI：

  10.1063/1.1739979