2,5-Dibromo-3-[2-[2-[2-(2-bromoethoxy)ethoxy]ethoxy]ethoxy]thiophene | 952411-29-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 噻吩类
• 英文名称: 2,5-Dibromo-3-[2-[2-[2-(2-bromoethoxy)ethoxy]ethoxy]ethoxy]thiophene
• 英文别名: 2,5-dibromo-3-[2-[2-[2-(2-bromoethoxy)ethoxy]ethoxy]ethoxy]thiophene
• CAS: 952411-29-9
• 化学式: C₁₂H₁₇Br₃O₄S
• 分子量: 497.043
• InChiKey: WBBUWXZUMISSRX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  20
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  65.2
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  3-(11-hydroxy-3,6,9-trioxa-1-undecoxy)thiophene 在 N-溴代丁二酰亚胺(NBS) 、 溶剂黄146 作用下， 以 四氢呋喃 为溶剂， 生成 2,5-Dibromo-3-[2-[2-[2-(2-bromoethoxy)ethoxy]ethoxy]ethoxy]thiophene
  参考文献：
  名称：

  [EN] POLYMERS WITH BODIPY-BASED BACKBONE FOR SOLAR CELLS
  [FR] POLYMÈRES AVEC SQUELETTE À BASE DE BODIPY POUR DES CELLULES SOLAIRES

  摘要：

  本申请公开了用于太阳能电池器件的BODIPY基骨架聚合物的制备。实施例提供了高效的溶液加工的大体异质结（"BHJ"）聚合物/PCBM太阳能电池，其中BODIPY基骨架聚合物（pBodipy和pBodipy-T）作为聚合物电子给体。在本申请的一些实施例中，太阳能电池展现出对太阳光谱高效的光吸收，达到约1.6eV。CV数据表明，这些基于BODIPY的骨架聚合物与PCBM接触时具有最佳的能级对齐，有深的HOMO能级，导致高达0.8V的高Voc和约2%的效率。

  公开号：

  WO2010075512A1

文献信息

• ENZYMATIC BIOSENSORS, HYDROGEL COMPOSITIONS THEREFOR, AND METHODS FOR THEIR PRODUCTION
  申请人：HITACHI CHEMICAL COMPANY AMERICA, LTD.

  公开号：US20190233869A1

  公开（公告）日：2019-08-01

  A biosensor ( 1 ) is disclosed that may include at least one electrode surface ( 3 ); a reagent layer ( 5 ) disposed on top of the at least one electrode surface ( 3 ) and a reagent layer ( 5 ) formed thereon. The reagent layer ( 5 ) is formed according to the principles of the present invention, and may include a redox enzyme, a redox polymer, and a cross-linked gel. The reagent layer ( 5 ) is structured to act as a conductive matrix that traps the redox polymer and enzyme at the electrode surface.
• [EN] REDOX MEDIATOR-FUNCTIONALIZED WATER-SOLUBLE POLYMER<br/>[FR] POLYMÈRE SOLUBLE DANS L'EAU FONCTIONNALISÉ PAR UN MÉDIATEUR REDOX
  申请人：HITACHI CHEMICAL CO AMERICA LTD

  公开号：WO2018039585A1

  公开（公告）日：2018-03-01

  Described herein are a series of water-soluble conjugated polymers having redox mediators and functional groups on flexible side chains. The polymers may include a backbone having a conjugated polymer; a first side chain attached to the backbone, the first side chain having a ferrocene group or a derivative thereof; a second side chain attached to the backbone, the second side chain having an organic acid, a salt of an organic acid, or quaternary ammonium; and at least one of the first and second side chains having at least one of a carbon atom, a nitrogen atom, an oxygen atom, and a sulfur atom. Because of their redox activity, water solubility and ease of further coupling with versatile functional species, the polymers discussed in this application can be used as sensor interface materials for various biosensor developments.
• [EN] ENZYMATIC BIOSENSORS, HYDROGEL COMPOSITIONS THEREFOR, AND METHODS FOR THEIR PRODUCTION<br/>[FR] BIO-CAPTEURS ENZYMATIQUES, COMPOSITIONS D'HYDROGEL POUR CEUX-CI ET LEURS PROCÉDÉS DE FABRICATION
  申请人：HITACHI CHEMICAL CO AMERICA LTD

  公开号：WO2018039572A1

  公开（公告）日：2018-03-01

  A biosensor (1) is disclosed that may include at least one electrode surface (3); a reagent layer (5) disposed on top of the at least one electrode surface (3) and a reagent layer (5) formed thereon. The reagent layer (5) is formed according to the principles of the present invention, and may include a redox enzyme, a redox polymer, and a cross- linked gel. The reagent layer (5) is structured to act as a conductive matrix that traps the redox polymer and enzyme at the electrode surface.
• [EN] POLYMERS WITH BODIPY-BASED BACKBONE FOR SOLAR CELLS<br/>[FR] POLYMÈRES AVEC SQUELETTE À BASE DE BODIPY POUR DES CELLULES SOLAIRES
  申请人：UNIV MICHIGAN TECH

  公开号：WO2010075512A1

  公开（公告）日：2010-07-01

  The present application discloses the preparation of BODIPY-based backbone polymers for use in solar cell devices. Embodiments provide efficient solution-processed bulk heterojunction ("BHJ") polymer/PCBM solar cells with BODIPY-based backbone polymers (pBodipy and pBodipy-T) as the polymer electron donor. In some embodiments of the present application, solar cells exhibit highly efficient light harvesting of the solar spectrum up to ~1.6eV. CV data suggest these BODIPY-based backbone polymers have an optimal energy level alignment for charge separation in contact with PCBM, and deep HOMO levels that result in the high Voc of 0.8 V and efficiency of about 2%.

  本申请公开了用于太阳能电池器件的BODIPY基骨架聚合物的制备。实施例提供了高效的溶液加工的大体异质结（"BHJ"）聚合物/PCBM太阳能电池，其中BODIPY基骨架聚合物（pBodipy和pBodipy-T）作为聚合物电子给体。在本申请的一些实施例中，太阳能电池展现出对太阳光谱高效的光吸收，达到约1.6eV。CV数据表明，这些基于BODIPY的骨架聚合物与PCBM接触时具有最佳的能级对齐，有深的HOMO能级，导致高达0.8V的高Voc和约2%的效率。