| 1551220-91-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 1551220-91-7
• 化学式: C₅₅H₇₇N₃O₅PdS
• 分子量: 998.719
• InChiKey: GJMWDDOVXOBHRU-GXDBEDQESA-M

反应信息

• 作为产物：
  描述：

  、 在 potassium carbonate 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 以71%的产率得到
  参考文献：
  名称：

  Enhancement of smectic C mesophase stability by using branched alkyl chains in the auxiliary ligands of luminescent Pt(II) and Pd(II) complexes

  摘要：

  A novel series of Pd(II) and Pt(II) complexes based on cyclometallated imine ligands and N-benzoylthiourea (BTU) derivatives as auxiliary ligands has been prepared and their liquid crystalline properties as well as photophysical properties have been investigated. The crystal structure of one cyclometallated Pt(II) complex with N-(p-F-phenyl)-N'-benzoylthiourea as a co-ligand has been solved. The liquid crystalline properties have been investigated by a combination of DSC, POM and variable temperature powder X-ray diffraction. These new metallomesogens display either a monotropic SmC phase or both SmA and SmC phases, depending on the number of alkoxy groups attached to the imine ligand, alkyl chain length or the use of branched alkoxy terminal groups. We found that the introduction of branched alkoxy terminal groups lead to lower transition temperatures and stabilization of the SmC phase in both the Pd(II) and Pt(II) complexes. While the Pd(II) complexes display no emission, the Pt(II) complexes show good emission properties in solution, in the solid state and as a PMMA film at room temperature, and their investigation is reported. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.11.015