1-[(4,5-Dimethoxy-2-nitrophenyl)-(2-nitrophenyl)methyl]-4,5-dimethoxy-2-nitrobenzene | 494868-60-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: 1-[(4,5-Dimethoxy-2-nitrophenyl)-(2-nitrophenyl)methyl]-4,5-dimethoxy-2-nitrobenzene
• 英文别名: 1-[(4,5-dimethoxy-2-nitrophenyl)-(2-nitrophenyl)methyl]-4,5-dimethoxy-2-nitrobenzene
• CAS: 494868-60-9
• 化学式: C₂₃H₂₁N₃O₁₀
• 分子量: 499.434
• InChiKey: KVHSGQFZRRCANH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  36
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  174
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  1-[(4,5-Dimethoxy-2-nitrophenyl)-(2-nitrophenyl)methyl]-4,5-dimethoxy-2-nitrobenzene 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 生成 2-(2,3,6,7-Tetramethoxy-acridin-9-yl)-phenylamine
  参考文献：
  名称：

  Brønsted- and Lewis acid-catalyzed cyclization giving rise to substituted anthracenes and acridines

  摘要：

  A versatile acid-catalyzed method for the preparation of symmetrically and unsymmetrically Substituted 9,10-diphenyl-anthracenes is explored. Diveratrylmethanes are prepared and converted into 10-plenylanthracene-9-carbaldehydes by Lewis acid catalysis and into 9-phenylacridines by reduction. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)01462-4
• 作为产物：
  描述：

  4,4′-((2-nitrophenyl)methylene)bis(1,2-dimethoxybenzene) 在 硝酸 作用下， 生成 1-[(4,5-Dimethoxy-2-nitrophenyl)-(2-nitrophenyl)methyl]-4,5-dimethoxy-2-nitrobenzene
  参考文献：
  名称：

  Brønsted- and Lewis acid-catalyzed cyclization giving rise to substituted anthracenes and acridines

  摘要：

  A versatile acid-catalyzed method for the preparation of symmetrically and unsymmetrically Substituted 9,10-diphenyl-anthracenes is explored. Diveratrylmethanes are prepared and converted into 10-plenylanthracene-9-carbaldehydes by Lewis acid catalysis and into 9-phenylacridines by reduction. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)01462-4

文献信息

• Brønsted- and Lewis acid-catalyzed cyclization giving rise to substituted anthracenes and acridines
  作者：Raf Goossens、Mario Smet、Wim Dehaen

  DOI：10.1016/s0040-4039(02)01462-4

  日期：2002.9

  A versatile acid-catalyzed method for the preparation of symmetrically and unsymmetrically Substituted 9,10-diphenyl-anthracenes is explored. Diveratrylmethanes are prepared and converted into 10-plenylanthracene-9-carbaldehydes by Lewis acid catalysis and into 9-phenylacridines by reduction. (C) 2002 Elsevier Science Ltd. All rights reserved.