| 1410789-21-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 苯丙酸
• CAS: 1410789-21-7
• 化学式: C₉H₈BrClO₄
• 分子量: 295.517
• InChiKey: QDSAGVUEUFDAKG-SSDOTTSWSA-N

反应信息

• 作为产物：
  描述：

  aeruginosin GE686 在 盐酸 、 水 作用下， 反应 16.0h， 生成 D-别异亮氨酸 、 、 L-Choi
  参考文献：
  名称：

  Bromine- and Chlorine-Containing Aeruginosins from Microcystis aeruginosa Bloom Material Collected in Kibbutz Geva, Israel

  摘要：

  Five new natural products, aeruginosins GE686 (1), GE766 (2), GE730 (3), GE810 (4), and GE642 (5), were isolated along with four known aeruginosins, 98C, 101, KY642, and DA688, from bloom material of the cyanobacterium Microcystis aeruginosa collected from a fish pond in Kibbutz Geva, Israel, in August 2007. Their structures were elucidated by a combination of various spectroscopic techniques, primarily NMR and MS, while the absolute configurations of the stereogenic centers were determined by Marfey's and chiral-phase HPLC methods. Two of the new aeruginosins, aeruginosins GE686 (1) and GE766 (2), contain the unprecedented D-m-Br-m'-Cl-p-hydroxyphenyllactic acid derivative. The structures and biological activities of the five new metabolites are described.

  DOI：

  10.1021/np3005612