[((3-tert-butyl-2-thiolato-5-methylphenyl)bis(3,5-dimethyl-1-pyrazolyl)methane)ZnSPh] | 247039-22-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [((3-tert-butyl-2-thiolato-5-methylphenyl)bis(3,5-dimethyl-1-pyrazolyl)methane)ZnSPh]
• CAS: 247039-22-1
• 化学式: C₂₈H₃₄N₄S₂Zn
• 分子量: 556.127
• InChiKey: DICOZTXSVLXXEX-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  (3-tert-butyl-2-mercapto-5-methylphenyl)bis(3,5-dimethyl-1-pyrazolyl)methane 以 二氯甲烷 、 甲苯 为溶剂， 生成 [((3-tert-butyl-2-thiolato-5-methylphenyl)bis(3,5-dimethyl-1-pyrazolyl)methane)ZnSPh]
  参考文献：
  名称：

  Synthesis and Characterization of Pseudotetrahedral N₂O and N₂S Zinc(II) Complexes of Two Heteroscorpionate Ligands:  Models for the Binding Sites of Several Zinc Metalloproteins

  摘要：

  Nine new pseudotetrahedral Zn(II) complexes of the heteroscorpionate ligands (3-tert-butyl-2-hydroxy(or thio)-5-methylphenyl)bis(3,5-dimethylpyrazolyl)methane, L1OH or L2SH, have been prepared and characterized (in most cases crystallographically). Complexes isolated include [(L1O)ZnCl]. [(L1O)ZnI], [(L1OH)ZnI2]. [(L1O)-ZnCH3,] [(L1O)ZnOAc], [(L1O)ZnSPh], [(L1O)ZnSBz], [(L2S)ZnCH3], [(L2S)ZnSPh], and [(L2S)(2)Zn]. In conjunction with the widely studied tris(pyrazolyl)borates this new series of heteroscorpionates provides a set of isolobal and isoelectronic ligands differing in donor set, i.e. N-3, N2O, and N2S. Preliminary reactivity studies with HX species, Mel, or trimethyl phosphate suggest differences between the three sets of ligands.

  DOI：

  10.1021/ic990233v