4,4'-(ethane-1,2-diyl)bis(3,5-dibromo-2,6-dimethylphenol) | 94400-04-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 4,4'-(ethane-1,2-diyl)bis(3,5-dibromo-2,6-dimethylphenol)
• 英文别名: 4,4'-(1,2-ethanediyl)bis(3,5-dibromo-2,6-dimethyl-phenol)；1,2-bis-(2,6-dibromo-3,5-dimethyl-4-hydroxyphenyl)ethane；4,4'-(1,2-ethanediyl)bis(3,5-dibromo-2,6-dimethylphenol)；1,2-bis(2,6-dibromo-3,5-dimethyl-4-hydroxyphenyl)ethane；3,5-Dibromo-4-[2-(2,6-dibromo-4-hydroxy-3,5-dimethylphenyl)ethyl]-2,6-dimethylphenol
• CAS: 94400-04-1
• 化学式: C₁₈H₁₈Br₄O₂
• 分子量: 585.956
• InChiKey: ASQUJLDEXYPPML-UHFFFAOYSA-N

物化性质

• 熔点：
  293-295 °C (decomp)
• 沸点：
  557.0±45.0 °C(Predicted)
• 密度：
  1.892±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.7
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4,4’-(ethane-1,2-diyl)bis(2,6-dimethylphenol) 生成 4,4'-(ethane-1,2-diyl)bis(3,5-dibromo-2,6-dimethylphenol)
  参考文献：
  名称：

  SILVIS, HARRY C.;MENDOZA, ABEL

  摘要：

  DOI：

文献信息

• Halogenated epoxy resins and advanced resins prepared therefrom
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0260571A2

  公开（公告）日：1988-03-23

  Halogenated aromatic epoxy resins are dis­closed wherein the halogen atoms are in the meta position with respect to a glycidyl ether group attached to an aromatic ring. Advanced epoxy resins are disclosed which result from the reaction of a relatively low molecular weight epoxy resin and a polyhydric phenol wherein at least one of the reactants contains at least one halogen atom which is meta with respect to a glycidyl ether group or a hydroxyl group attached to an aromatic ring. These advanced epoxy resins, when cured with a suitable curing agent, possess an improvement as compared to an advanced epoxy resin containing halogen atoms which are ortho with respect to a glycidyl ether group in at least one of thermal stability, glass transition temperature, relationship of viscosity to molecular weight and resistance to forming hydrolyzed halides in the presence of a refluxing solution of an alkali metal hydroxide.

  本发明公开了卤代芳香族环氧树脂，其中的卤素原子相对于连接到芳香环上的缩水甘油醚基团而言处于元位置。 已公开的高级环氧树脂是由分子量相对较低的环氧树脂和多羟基酚反应而成，其中至少一种反应物含有至少一个卤原子，该卤原子相对于缩水甘油醚基团或连接到芳香环上的羟基而言处于偏位。这些高级环氧树脂用适当的固化剂固化后，与含有卤素原子的高级环氧树脂相比，至少在热稳定性、玻璃化温度、粘度与分子量的关系以及在碱金属氢氧化物的回流溶液存在下形成水解卤化物的耐受性等方面有改善。
• Gray, Michael J.; Hartshorn, Michael P.; Vaughan, John, Australian Journal of Chemistry, 1984, vol. 37, # 10, p. 2027 - 2036
  作者：Gray, Michael J.、Hartshorn, Michael P.、Vaughan, John、Wright, Graeme J.

  DOI：——

  日期：——
• Polyfunctional vinylbenzyl ethers of polyhydric halogenated phenolic compoundsand copolymer compositions containing them
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0258695B1

  公开（公告）日：1991-11-27
• GRAY, M. J.;HARTSHORN, M. P.;VAUGHAN, J.;WRIGHT, G. J., AUSTRAL. J. CHEM., 1984, 37, N 10, 2027-2036
  作者：GRAY, M. J.、HARTSHORN, M. P.、VAUGHAN, J.、WRIGHT, G. J.

  DOI：——

  日期：——
• MENDOZA, ABEL
  作者：MENDOZA, ABEL

  DOI：——

  日期：——