| 1257333-50-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• CAS: 1257333-50-8
• 化学式: C₅₆H₃₂CuN₈
• 分子量: 880.47
• InChiKey: AWOWZGVIGAHORB-PLDNTTLQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  dichloro(cycloocta-1,5-diene)palladium (II) 、 以 二氯甲烷 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Bimetallic complexes of porphyrinphenanthroline: Preparation and catalytic activities

  摘要：

  Condensation of tetraphenylporphyrin-2,3-dione with 1,10-phenanthroline-5,6-diamine provided porphyrinphenanthroline (2) as the desired ligand. Metallation of the porphyrinic site of 2 with CoCl(2), NiCl(2), ZnCl(2) and CuCl(2) afforded the corresponding metal complexes [Co(2)] (8a), [Ni(2)] (8b), [Zn(2)] (8c) and [Cu(2)] (8d), respectively. Subsequent reactions of these metalloporphyrins with [(COD) PdCl(2)] yielded the corresponding bimetallic complexes [Co/Pd (9a), Ni/Pd (9b), Zn/Pd (9c) and Cu/Pd (9d)] in high yields. The bimetallic complex 9e (Mg/Pd) was prepared directly by complexation of 2 with MgBr(2) and [(COD) PdCl2]. All complexes were characterized by both spectroscopic and elemental analyses. In addition, crystal structure of 9c was determined to confirm its formulation. The use of these bimetallic complexes as pre-catalysts for Mizoroki-Heck coupling reaction has been examined. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.07.008
• 作为产物：
  描述：

  Cu(2+)-nitro-α,β,γ,δ-tetraphenylporphine 在 盐酸 、 硫酸 、 copper diacetate 、 三氟乙酸 、 tin(ll) chloride 作用下， 以 甲醇 、 二氯甲烷 、 水 为溶剂， 反应 61.63h， 生成
  参考文献：
  名称：

  Bimetallic complexes of porphyrinphenanthroline: Preparation and catalytic activities

  摘要：

  Condensation of tetraphenylporphyrin-2,3-dione with 1,10-phenanthroline-5,6-diamine provided porphyrinphenanthroline (2) as the desired ligand. Metallation of the porphyrinic site of 2 with CoCl(2), NiCl(2), ZnCl(2) and CuCl(2) afforded the corresponding metal complexes [Co(2)] (8a), [Ni(2)] (8b), [Zn(2)] (8c) and [Cu(2)] (8d), respectively. Subsequent reactions of these metalloporphyrins with [(COD) PdCl(2)] yielded the corresponding bimetallic complexes [Co/Pd (9a), Ni/Pd (9b), Zn/Pd (9c) and Cu/Pd (9d)] in high yields. The bimetallic complex 9e (Mg/Pd) was prepared directly by complexation of 2 with MgBr(2) and [(COD) PdCl2]. All complexes were characterized by both spectroscopic and elemental analyses. In addition, crystal structure of 9c was determined to confirm its formulation. The use of these bimetallic complexes as pre-catalysts for Mizoroki-Heck coupling reaction has been examined. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.07.008