| 1564278-26-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• CAS: 1564278-26-7
• 化学式: Br*C₄₆H₄₅BNO₄
• 分子量: 766.583
• InChiKey: ZLJPGBKATRLMNB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  6.02
• 重原子数：
  53.0
• 可旋转键数：
  10.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  40.8
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  在 双氧水 作用下， 以 aq. buffer 为溶剂， 反应 1.0h， 生成 4-(4-(2,2-双(4-甲氧基苯基)-1-苯基乙烯基)苯基)吡啶
  参考文献：
  名称：

  A highly selective fluorescence turn-on detection of hydrogen peroxide and d-glucose based on the aggregation/deaggregation of a modified tetraphenylethylene

  摘要：

  A new selective fluorescence turn-on detection of hydrogen peroxide was established by taking advantage of the aggregation induced-emission (AIE) behavior of tetraphenylethylene unit and the reaction of hydrogen peroxide toward the arylboronic ester group in compound 1. Moreover, compound 1 was successfully utilized for the selective detection of D-glucose in aqueous solution. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.01.056
• 作为产物：
  描述：

  4-(4-(2,2-双(4-甲氧基苯基)-1-苯基乙烯基)苯基)吡啶 、 4-溴甲基苯硼酸频哪醇酯 以 乙腈 为溶剂， 反应 7.0h， 以95.6%的产率得到
  参考文献：
  名称：

  A highly selective fluorescence turn-on detection of hydrogen peroxide and d-glucose based on the aggregation/deaggregation of a modified tetraphenylethylene

  摘要：

  A new selective fluorescence turn-on detection of hydrogen peroxide was established by taking advantage of the aggregation induced-emission (AIE) behavior of tetraphenylethylene unit and the reaction of hydrogen peroxide toward the arylboronic ester group in compound 1. Moreover, compound 1 was successfully utilized for the selective detection of D-glucose in aqueous solution. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.01.056