1,4-bis[[(2'-m-picolylaminoformyl)phenoxyl]methyl]naphthalene | 1115205-18-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,4-bis[[(2'-m-picolylaminoformyl)phenoxyl]methyl]naphthalene
• 英文别名: N-(pyridin-3-ylmethyl)-2-[[4-[[2-(pyridin-3-ylmethylcarbamoyl)phenoxy]methyl]naphthalen-1-yl]methoxy]benzamide
• CAS: 1115205-18-9
• 化学式: C₃₈H₃₂N₄O₄
• 分子量: 608.696
• InChiKey: HJLWWFCWSJUMBE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  46
• 可旋转键数：
  12
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  102
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  europium(III) nitrate hexahydrate 、 1,4-bis[[(2'-m-picolylaminoformyl)phenoxyl]methyl]naphthalene 、 水 以 氯仿 、 乙酸乙酯 为溶剂， 生成 [[Eu(1,4-bis[[(2'-m-picolylaminoformyl)phenoxyl]methyl]naphthalene)(nitrate)3(water)](water)]n
  参考文献：
  名称：

  Assembly of a novel luminescent coordination polymer from europium nitrate and a new semirigid bridging podand

  摘要：

  One-dimensional zig-zag coordination polymer has been rationally assembled by the reaction of europium nitrate and a new amide type semirigid bridging podand 1,4-bis{[(2'-m-picolylaminoformyl)phenoxyl]methyl}naphthalene (L). The coordination chains are further linked by the intermolecular hydrogen bonds to form two-dimensional supramolecular layer structure. At the same time, the luminescent properties of the Eu(111) complex were also investigated. Under the excitation, the complex exhibited characteristic emissions of europium ion. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.09.026