1,7-bis(tributylstannyl)-1,6-heptadiyne | 1222989-87-8

• 分子结构分类: 有机化合物 - 乙炔化物 - 碳化物
• 英文名称: 1,7-bis(tributylstannyl)-1,6-heptadiyne
• 英文别名: Tributyl(7-tributylstannylhepta-1,6-diynyl)stannane；tributyl(7-tributylstannylhepta-1,6-diynyl)stannane
• CAS: 1222989-87-8
• 化学式: C₃₁H₆₀Sn₂
• 分子量: 670.237
• InChiKey: BXUWTZMHBHZQBP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.3
• 重原子数：
  33
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.68
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1,7-bis(tributylstannyl)-1,6-heptadiyne 在 titanium(IV) isopropylate 、 异丙基氯化镁 作用下， 以 乙醚 为溶剂， 反应 5.0h， 生成
  参考文献：
  名称：

  Synthesis and Charge-Carrier Transport Properties of Poly(phosphole P-alkanesulfonylimide)s

  摘要：

  A new class of polyphospholes bearing alkanesulfonylimino moieties on the phosphorus(V) centers was prepared by the Pd-Cul-promoted Stille coupling reaction to investigate the charge-carrier transport properties of the pi-networks of polyphospholes. Time-of-flight measurements have revealed that the poly(phosphole P-imide)s possess ambipolar charge-carrier mobilities of up to mu(electron) = 6 x 10(-3) cm(2) V-1 s(-1) and mu(hole) = 4 x 10(-3) cm(2) V-1 s(-1).

  DOI：

  10.1021/ol4000982

文献信息

• Synthesis and Charge-Carrier Transport Properties of Poly(phosphole <i>P</i>-alkanesulfonylimide)s
  作者：Yoshihiro Matano、Hiroshi Ohkubo、Yoshihito Honsho、Arihiro Saito、Shu Seki、Hiroshi Imahori

  DOI：10.1021/ol4000982

  日期：2013.2.15

  A new class of polyphospholes bearing alkanesulfonylimino moieties on the phosphorus(V) centers was prepared by the Pd-Cul-promoted Stille coupling reaction to investigate the charge-carrier transport properties of the pi-networks of polyphospholes. Time-of-flight measurements have revealed that the poly(phosphole P-imide)s possess ambipolar charge-carrier mobilities of up to mu(electron) = 6 x 10(-3) cm(2) V-1 s(-1) and mu(hole) = 4 x 10(-3) cm(2) V-1 s(-1).