Naphthylen-2,6-diisocyanat | 132216-63-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: Naphthylen-2,6-diisocyanat
• 英文别名: 1,6-naphthalene diisocyanate；1,6-diisocyanatonaphthalene
• CAS: 132216-63-8
• 化学式: C₁₂H₆N₂O₂
• 分子量: 210.192
• InChiKey: UCQKVUHVADPLBH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  58.9
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• Method for synthesis of aliphatic isocyanates from aromatic isocyanates
  申请人：DEGUSSA AG

  公开号：US20040097752A1

  公开（公告）日：2004-05-20

  The invention relates to a method for synthesis of aliphatic isocyanates from aromatic isocyanates in substantially 3 stages. In particular, the invention relates to a method for synthesis of bis{4-isocyanatocyclohexyl}methane (H 12 MDI) from bis{4-isocyanatophenyl}methane (MDI). More especially, the invention relates to a method for synthesis of H 12 MDI with a trans-trans isomer content of <30%, preferably of <20%, particularly preferably of 5 to 15%.

  本发明涉及一种从芳香族异氰酸酯合成脂肪族异氰酸酯的方法，大致分为三个阶段。具体而言，本发明涉及一种从双(4-异氰酸苯基)甲烷(MDI)合成双(4-异氰酸环己基)甲烷(H12MDI)的方法。尤其是，本发明涉及一种合成H12MDI的方法，其反式-反式异构体含量小于30％，优选小于20％，特别优选为5至15％。
• Membrane modified hydrogels, process for their manufacture and their use as active agent dispenser
  申请人：CIBA-GEIGY AG

  公开号：EP0046136A2

  公开（公告）日：1982-02-17

  Non-uniform water-insoluble interpenetrating polymer blend compositions comprising a first permeable water swellable polymer substrate interpenetrated in a gradient substantially normal to the substrate surface by a second less permeable condensation polymer to form a diffusion rate controlling membrane therein. Such compositions are useful as polymers with reduced permeabilities for water and organic solvents and therefore for the controlled delivery of active ingredients such as fragrances and bioaffecting agents into air or aqueous environments, or in membrane separation processes.

  非均匀水不溶性互穿聚合物混合物组合物，包括第一种可渗透水膨胀聚合物基材，在基材表面与第二种渗透性较低的缩合聚合物呈梯度互穿，以在其中形成扩散速率控制膜。这种混合物可用作降低水和有机溶剂渗透性的聚合物，因此可用于将活性成分（如香料和生物影响剂）有控制地输送到空气或水环境中，或用于膜分离过程。
• Improvements in or relating to siloxanes
  申请人：M & T CHEMICALS, INC.

  公开号：EP0054426A2

  公开（公告）日：1982-06-23

  The properties of polymeric compositions can be improved by the presence of a polysiloxane unit of formula where Q is a substituted or unsubstituted aromatic group, D is unsubstituted or substituted hydrocarbylene R1, R2, R3, R4, R5 and R6 each, independently, is unsubstituted or substituted hydrocarbyl. x, y and z each independently has a value from 0 to 100. Polyimides containing these units display improved solubility and adhesion; they are useful, among other things, as protective coatings.

  聚合体组合物的性能可以通过存在式中的聚硅氧烷单元得到改善 式中 Q 是取代或未取代的芳香基团、 D为未取代或取代的烃基 R1、R2、R3、R4、R5 和 R6 各自独立地为未取代或取代的烃基。 x、y 和 z 各自独立地具有 0 至 100 之间的数值。 含有这些单元的聚酰亚胺具有更好的溶解性和粘附性，可用作保护涂层等。
• Silicone-urethane copolymers
  申请人：UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

  公开号：EP0405494A2

  公开（公告）日：1991-01-02

  Linear silicone-urethane copolymers which contain tertiary amine or quaternary ammonium groups on the polymer backbone of the general formula: [R′NR˝SiMe₂(OSiMe₂)bOSiMe₂R˝NR′CONHR˝NHCO₂(Y)O₂CNHR˝NHCO] wherein Me represents a methyl group; R′ represents a hydrogen atom or a lower alkyl group having one to three carbon atoms; R˝ represents a divalent hydrocarbon group having at least three carbon atoms such as (CH₂)₃₋₁₂; and Y represents (CzH2z+1N) where Z ≧ 5 and ≦ 22 and may be quaternized by use of a quaternizing agent R′X wherein X is selected from the group consisting of a halide atom, an acetate or higher carboxylate group, and an alkylsulfate group where the alkyl moiety has 1 to 12 carbon atoms and where R′, R˝ and b may vary within each copolymer are described. These copolymers may be cast from organic solvents or from aqueous dispersions, providing films which possess high degrees of clarity and unexpectedly high strength and elasticity.

  线性硅酮-聚氨酯共聚物，其聚合物骨架上含有通式为 [R′NR˝SiMe₂(OSiMe₂)bOSiMe₂R˝NR′CONHR˝NHCO₂(Y)O₂CNHR˝NHCO]。 其中 Me 代表甲基；R′ 代表氢原子或具有一至三个碳原子的低级烷基；R˝ 代表至少具有三个碳原子的二价烃基，如 (CH₂)₃₋₁₂；和 Y 代表 (CzH2z+1N)，其中 Z ≧ 5 和 ≦ 22，并可通过使用季铵化剂 R′X 季铵化，其中 X 选自卤原子、醋酸酯或高羧酸酯基团和烷基硫酸酯基团组成的组，其中烷基具有 1 至 12 个碳原子，R′、R˝ 和 b 可在每种共聚物中变化。这些共聚物可以从有机溶剂或水性分散体中浇铸，从而提供具有高透明度、出乎意料的高强度和高弹性的薄膜。
• Crosslinkable polyester/isocyanate compositions suitable for the preparation of composite materials
  申请人：Montedison S.p.A.

  公开号：EP0445837A2

  公开（公告）日：1991-09-11

  Disclosed are crosslinkable polymeric compositions which show a low content of vinyl monomers, are suitable for the fabrication of composite materials having good mechanical properties and comprise: (A)a liquid polyisocyanate; (B)a polyol having a maximum functionality of 7 and an average molecular weight of from about 200 to about 10,000; (C)a vinylester resin or unsaturated polyester resin; (D)a radical polymerization initiator stable at temperatures below 70°C; (E)a decomposition promoter for the initiator (D); (F)a trimerization catalyst for the isocyanate (A); (G)optionally, a mineral filler having dehydrating properties.

  所公开的可交联聚合物组合物中乙烯基单体的含量较低，适用于制造具有良好机械性能的复合材料，其中包括 (A) 液体多异氰酸酯； (B)一种多元醇，其最大官能度为 7，平均分子量约为 200 至 10 000； (C) 乙烯酯树脂或不饱和聚酯树脂； (D) 在低于 70°C 的温度下稳定的自由基聚合引发剂； (E)引发剂(D)的分解促进剂 (F) 异氰酸酯 (A) 的三聚催化剂； (G) 可选的具有脱水特性的矿物填料。