| 1397685-17-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• CAS: 1397685-17-4
• 化学式: C₃₀H₃₃N₂OS*Cl
• 分子量: 505.124
• InChiKey: ZMXNXENZYILHNJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.78
• 重原子数：
  35.0
• 可旋转键数：
  4.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  19.39
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  1-(9-(5-phenyl-1,3-dithian-2-yl)-6-(piperidin-1-yl)-3H-xanthen-3-ylidene)piperidin-1-ium chloride 生成
  参考文献：
  名称：

  Carbon–Carbon Bond Cleavage in Fluorescent Pyronin Analogues Induced by Yellow Light

  摘要：

  A novel class of pyronin analogues, which undergoes a photochemically induced cleavage of the C-C bond in the presence of water in both solution and on a silica gel surface upon direct irradiation with visible fight, is reported. The reaction course can be monitored by characteristic fluorescence of both the starting compound and the final product. This system could find useful applications in the field of photoremovable protecting groups or caged fluorophores.

  DOI：

  10.1021/ol302244f