copper(I) salt of O,O-dibutylthiophosphoric acid | 91219-56-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫代磷酸及其衍生物
• 英文名称: copper(I) salt of O,O-dibutylthiophosphoric acid
• 英文别名: copper(1+);dibutoxy-oxido-sulfanylidene-λ5-phosphane
• CAS: 91219-56-6
• 化学式: C₈H₁₈O₃PS*Cu
• 分子量: 288.815
• InChiKey: ZDBJOQSUAJOBSZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  14.0
• 可旋转键数：
  8.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  41.52
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  potassium O,O-dibutyl phosphorothioate 、 氯化亚铜 以69%的产率得到
  参考文献：
  名称：

  VIXREVA, L. A.;PUDOVA, T. A.;BABASHEVA, K. K.;DARISHEVA, A. M.;MATROSOV, +, DOKL. AN CCCP, 1984, 274, N 4, 822-826

  摘要：

  DOI：

文献信息

• Vikhreva, L. A.; Pudova, T. A.; Babasheva, K. K., Doklady Chemistry, 1984, vol. 274, p. 43 - 46
  作者：Vikhreva, L. A.、Pudova, T. A.、Babasheva, K. K.、Darisheva, A. M.、Matrosov, E. I.、et al.

  DOI：——

  日期：——
• ——
  作者：N. N. Godovikov

  DOI：10.1023/a:1011302010426

  日期：——

  The results of searching fbr the methods of synthesis of substituted thioethynyl monothio- and dithiophosphates, which are of interest as physiologically active compounds, are summarized. The preparative method for the synthesis of thioesters of O, O-dialkylmonothiophosphoric acids of a specific type was developed: the reaction of substituted ethynyl bromides with potassium salts of the corresponding monothiophosphoric acids in the presence of an equimolar amount of CuCl. These reactions occur through the stage of formation of Cu-I salts of the corresponding monothiophosphoric acids and are accompanied by redox processes leading to the formation of free radicals. The modified method for the synthesis of substituted thioethynyl monothio- and dithiophosphates is the reaction of Cu-I salts of these acids with the corresponding ethynyl bromides.