5-Acetyl-1,4-dimethoxynaphthalene | 118761-63-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 5-Acetyl-1,4-dimethoxynaphthalene
• 英文别名: 1-(5,8-Dimethoxy-1-naphthyl)ethanone；1-(5,8-dimethoxynaphthalen-1-yl)ethanone
• CAS: 118761-63-0
• 化学式: C₁₄H₁₄O₃
• 分子量: 230.263
• InChiKey: QYCPCTSAMIMLQQ-UHFFFAOYSA-N

物化性质

• 沸点：
  387.2±22.0 °C(Predicted)
• 密度：
  1.133±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-<(1'-ethoxy)ethoxy> propionitrile 、 alkaline earth salt of/the/ methylsulfuric acid 生成 5-Acetyl-1,4-dimethoxynaphthalene
  参考文献：
  名称：

  Thermodynamic control of regioselectivity in the addition of carbanions to (arene)tricarbonylchromium complexes

  摘要：

  DOI：

  10.1021/ja00187a039

文献信息

• Kuendig, E. Peter; Desobry, Vincent; Simmons, Dana P., Journal of the American Chemical Society, 1989, vol. 111, p. 1804 - 1814
  作者：Kuendig, E. Peter、Desobry, Vincent、Simmons, Dana P.、Wenger, Eric

  DOI：——

  日期：——
• Thermochromic Furofurans. IV. Approach to the synthesis of bridgehead substituted furo[3,2-b]furans and side products of McMurry reactions
  作者：Hartmut Laatsch、Antti Talvitie、Andreas Kral、Bernd-Peter Ernst、Mathias Noltemeyer

  DOI：10.1002/prac.19963380127

  日期：——

  Substituted dihydroxystilbenes 2 are suitable starting materials for the synthesis of photochromic systems derived from 3/4. Attempts to couple the naphthones 8a-8e by the McMurry reaction with TiCl3/LiAlH4 yielded mainly reduction products such as 8f, g or 9. However, the furofuran 3b was isolated when using the zinc-copper couple for reduction. The helicene 11 was formed as an unexpected byproduct in the McMurry reaction of the pivaloylnaphthalene 8d.
• Thermodynamic control of regioselectivity in the addition of carbanions to (arene)tricarbonylchromium complexes
  作者：E. Peter Kuendig、Vincent Desobry、Dana P. Simmons、Eric Wenger

  DOI：10.1021/ja00187a039

  日期：1989.3