bis(2-hydroxybenzylamine-2'-hydroxynaphthylideno)tetraaquacerium(III) nitrate | 570370-74-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: bis(2-hydroxybenzylamine-2'-hydroxynaphthylideno)tetraaquacerium(III) nitrate
• CAS: 570370-74-0
• 化学式: C₃₆H₃₆CeN₂O₈*NO₃
• 分子量: 826.815
• InChiKey: NLOXRXZKOWGUOV-VSFYUWJPSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-hydroxy-1-naphthaldehyde-o-hydroxybenzyl amine 、 水 、 cerous nitrate 以 乙醇 为溶剂， 以70.1%的产率得到bis(2-hydroxybenzylamine-2'-hydroxynaphthylideno)tetraaquacerium(III) nitrate
  参考文献：
  名称：

  Metal Chelates of Cerium(III), Thorium(IV), and Dioxouranium(VI); Complexes with Some Derivatives of Aryl Schiff Bases

  摘要：

  New Ce(III), Th(IV) and U(VI) complexes with the aryl Schiff bases 2-hydroxybenzylamine-2'-hydroxybenzylidene (HL1), -2'-hydroxynaphthylidene (HL2), -2'-hydroxy-5'-bromobenzylidene (HL1), -2'-hydroxy-5'-chlorobenzylidene (HL4), 2'-hydroxy-3',5'-dichlorobenzylidene (HL5) and 2'-hydroxy-3-methoxybenzylidene (HL6) have been synthesized and characterized by elemental and thermal analyses, molar conductance, magnetic susceptibility, IR, H-1 NMR and electronic spectra. Elemental analyses along with conductometric titrations showed the formation of 1:1 and 1:2 (M:L) complexes while IR, molar conductance and H-1 NMR data proved that these ligands act as monobasic, tridentates for the 1: 1 and monobasic, bidentates for the 1:2 complexes with a coordination number of eight in both.

  DOI：

  10.1081/sim-120019998