biotin tetrabutylammonium salt 、 N1-[7-(3-[(3-([1-([7-(acetylamino)[1,8]naphthyridin-2-yl]methyl)pyridinium-3-yl]aminocarbonyl)benzoyl)amino]pyridinium-1-ylmethyl)[1,8]naphthyridin-2-yl]acetamide dihexafluorophosphate 以
二甲基亚砜 为溶剂,
生成
参考文献:
名称:
Naphthyridine-based symmetrical and unsymmetrical pyridinium amides in sensing of biotin salt
摘要:
Two naphthyridine-based receptors have been designed and synthesised for biotin salt. The compounds serve as good hosts for the detection of biotin carboxylate rather than biotin ester. The correct dispositions of the binding groups under an isophthaloyl spacer enable the receptors to bind both the cyclic urea and the carboxylate ends simultaneously with moderate binding constant values. The receptors are effective for the binding of tetrabutylammonium salt of biotin with a concomitant increase in the fluorescence of naphthyridine and show appreciable binding of biotin salt in CH3CN containing 1.2% DMSO. The binding was monitored in CH3CN containing 1.2% DMSO and DMSO using H-1 NMR, UV-vis and fluorescence spectroscopic methods.