2,9-dimethyldinaphtho[2,3-b:2',3'-f]thieno[3,2-b]thienophene | 1021604-10-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2,9-dimethyldinaphtho[2,3-b:2',3'-f]thieno[3,2-b]thienophene
• 英文别名: 2,8-DMeDNTT；7,19-dimethyl-12,24-dithiahexacyclo[11.11.0.02,11.04,9.014,23.016,21]tetracosa-1(13),2(11),3,5,7,9,14(23),15,17,19,21-undecaene
• CAS: 1021604-10-3
• 化学式: C₂₄H₁₆S₂
• 分子量: 368.523
• InChiKey: XIMJEGOVJIKJIH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  26
• 可旋转键数：
  0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,2-bis(6-methyl-3-methylthio-2-naphthyl)ethylene 在 碘 作用下， 以 氯仿 为溶剂， 反应 22.0h， 以15%的产率得到2,9-dimethyldinaphtho[2,3-b:2',3'-f]thieno[3,2-b]thienophene
  参考文献：
  名称：

  NOVEL FUSED-RING AROMATIC COMPOUND, PROCESS FOR PRODUCING THE SAME, AND USE THEREOF

  摘要：

  公开号：

  EP2098527B1

文献信息

• Compounds Having Semiconducting Properties and Related Compositions and Devices
  申请人：Usta Hakan

  公开号：US20130062598A1

  公开（公告）日：2013-03-14

  Disclosed are new compounds having semiconducting properties. Such compounds can be processed in solution-phase at a temperature of less than about 50° C. into thin film semiconductors that exhibit high carrier mobility and/or good current modulation characteristics.

  揭示了具有半导体特性的新化合物。这些化合物可以在溶液相中以低于约50°C的温度加工成薄膜半导体，表现出高载流子迁移率和/或良好的电流调制特性。
• NOVEL FUSED POLYCYCLIC AROMATIC COMPOUND, PROCESS FOR PRODUCING THE SAME, AND USE THEREOF
  申请人：Takimiya Kazuo

  公开号：US20100065826A1

  公开（公告）日：2010-03-18

  In one embodiment of the present invention, a novel fused polycyclic aromatic compound of the present invention is (a) a compound including a benzodichalcogenophenobenzodichalcogenophene (BXBX) skeleton further having an aromatic ring(s) located outside the BXBX skeleton, or (b) a compound including a BXBX skeleton in which a benzene ring is substituted with a heterocyclic ring. The compound can strengthen intermolecular interaction due to greater π electron orbits. This improves an electron field effect mobility of an organic semiconductor device that is manufactured by use of the compound as an organic semiconductor material. Further, since the number of fused rings included in the compound is small, the compound does not cause problems that generally occur in compounds having an extremely large number of fused rings, i.e., poor solubility in solvent and poor atmospheric stability due to high affinity to oxygen. As a result, the fused polycyclic aromatic compound of the present invention can be preferably used as an organic semiconductor material.

  在本发明的一种实施例中，本发明的新型融合多环芳香化合物是(a) 包括苯二卤素苯并二卤素苯并二卤素苯（BXBX）骨架，进一步具有位于BXBX骨架外部的芳香环，或者(b) 包括一个BXBX骨架，在其中苯环被杂环环取代的化合物。该化合物可以通过更大的π电子轨道强化分子间相互作用。这提高了由该化合物作为有机半导体材料制造的有机半导体器件的电子场效应迁移率。此外，由于化合物中包含的融合环数较少，因此该化合物不会引起通常出现在具有极大融合环数的化合物中的问题，即对溶剂的溶解度差和对氧气亲和力高导致的大气稳定性差。因此，本发明的融合多环芳香化合物可作为有机半导体材料优选使用。
• Method For Producing Aromatic Compound
  申请人：NIPPON KAYAKU KABUSHIKI KAISHA

  公开号：US20150239901A1

  公开（公告）日：2015-08-27

  A method for producing a heterocyclic compound represented by general formula (2) from a heterocyclic compound represented by general formula (1) (in the formulae, X1 represents a halogen atom; each of Y1 and Y2 independently represents an oxygen atom, sulfur atom, or selenium atom; each of R1 and R2 independently represents a substituent; m and n respectively represent the number of substituents R1 and R2, each of m and n representing an integer of 0-4; and when m and n are 2 or higher, R1 and R2 may be the same or different and may bond to each other to form an optionally substituted ring).

  一种从一般式（1）所表示的杂环化合物中制备一般式（2）所表示的杂环化合物的方法（在公式中，X1代表卤素原子；每个Y1和Y2分别表示氧原子、硫原子或硒原子；每个R1和R2分别表示取代基；m和n分别表示取代基R1和R2的数量，m和n分别表示0-4的整数；当m和n都为2或更高时，R1和R2可以相同或不同，并且可以连接以形成一个可选的取代环）。
• COMPOSITION FOR FORMING ORGANIC SEMICONDUCTOR FILM, ORGANIC SEMICONDUCTOR FILM AND METHOD FOR MANUFACTURING SAME, AND ORGANIC SEMICONDUCTOR COMPOUND
  申请人：Fujifilm Corporation

  公开号：EP3193383A1

  公开（公告）日：2017-07-19

  Objects of the present invention are to provide a composition for forming an organic semiconductor film that has excellent preservation stability and makes the obtained organic semiconductor element exhibit excellent driving stability in the atmosphere, to provide an organic semiconductor film using the composition for forming an organic semiconductor film, a method for manufacturing the organic semiconductor film, an organic semiconductor element, a method for manufacturing the organic semiconductor element, and to provide a novel organic semiconductor compound. A composition for forming an organic semiconductor film of the present invention contains a specific organic semiconductor having an alkoxyalkyl group as a component A and a solvent as a component B, in which a content of a non-halogen-based solvent is equal to or greater than 50% by mass with respect to a total content of the component B, and a content of the component A is equal to or greater than 0.7% by mass and less than 15% by mass.

  本发明的目的是提供一种用于形成有机半导体薄膜的组合物，该组合物具有优异的保存稳定性，并使获得的有机半导体元件在大气中表现出优异的驱动稳定性；提供一种使用该用于形成有机半导体薄膜的组合物的有机半导体薄膜、一种制造该有机半导体薄膜的方法、一种有机半导体元件、一种制造该有机半导体元件的方法，以及提供一种新型有机半导体化合物。 本发明的一种用于形成有机半导体薄膜的组合物含有一种特定的有机半导体，该半导体具有作为组分 A 的烷氧基烷基和作为组分 B 的溶剂，其中非卤基溶剂的含量相对于组分 B 的总含量等于或大于 50%（按质量计），而组分 A 的含量等于或大于 0.7%（按质量计）且小于 15%（按质量计）。
• ELECTROLUMINESCENT THIOPHENE DERIVATIVES
  申请人：Lomox Limited

  公开号：EP2483367B1

  公开（公告）日：2015-09-16