bis(acetato-κ2O,O')(2,9-dimethyl-1,10-phenantroline-κ2N,N')mercury(II) | 791609-53-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: bis(acetato-κ2O,O')(2,9-dimethyl-1,10-phenantroline-κ2N,N')mercury(II)
• CAS: 791609-53-5
• 化学式: C₁₈H₁₈HgN₂O₄
• 分子量: 526.942
• InChiKey: CKOWTCCPEMJFJY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  新铜试剂 、 mercury(II) diacetate 在 potassium persulfate 作用下， 以 甲醇 、 水 为溶剂， 生成 bis(acetato-κ2O,O')(2,9-dimethyl-1,10-phenantroline-κ2N,N')mercury(II)
  参考文献：
  名称：

  Bis(acetato-κ²O,O′)(2,9-dimethyl-1,10-phenanthroline-κ²N,N′)mercury(II) in two differently hydrated crystal forms

  摘要：

  Two differently hydrated crystal forms of the title compound, viz. bis(acetato-kappa(2)O,O')(2,9-dimethyl-1,10-phenanthroline-kappa(2)N,N')mercury(II), [Hg(C2H3O2)(2)(C14H12N2)] or [HgAc2(dmph)] [dmph is 2,3-dimethyl-1,10-phenantroline (neo-cuproine) and Ac is acetate], (I), and tris[bis(acetato-kappa(2)O,O')-(2,9-dimethyl-1,10-phenanthroline-kappa(2)N,N') mercury(II)] hexadecahydrate, [Hg(C2H3O2)(2)(C14H12N2)](3).16H(2)O or [HgAc2(dmph)](3) .16H(2)O, (II), are presented. Both structures are composed of very simple monomeric units, which act as the building blocks of complex packing schemes stabilized by a diversity of pi-pi and hydrogen-bonding interactions.

  DOI：

  10.1107/s0108270104014131