N,N',N,N'-Diethylendipyrrolidinium-dikation | 184-06-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 英文名称: N,N',N,N'-Diethylendipyrrolidinium-dikation
• 英文别名: 5,8-diazoniadispiro[4.2.4.2]tetradecane dication；5lambda(5),8lambda(5)-Diazadispiro(4.2.4.2)tetradecane；5,8-diazoniadispiro[4.2.48.25]tetradecane
• CAS: 184-06-5
• 化学式: C₁₂H₂₄N₂
• 分子量: 196.336
• InChiKey: MUJATFRBSGQYJY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  copper(l) iodide 、 N,N',N,N'-Diethylendipyrrolidinium-dikation 、 potassium iodide 以 甲醇 、 水 、 N,N-二甲基甲酰胺 为溶剂， 以62%的产率得到[(Cu3I5)(5,8-diazoniadispiro[4.2.4.2]tetradecane)]
  参考文献：
  名称：

  Self-Assembly, Crystal Structure and Thermal Property of a Coordination Polymer [(DDTD)(Cu₃I₅)]_n

  摘要：

  A novel coordination polymer [(DDTD)(Cu3I5)](n)(DDTD = 5, 8-diazoniadispiro[4.2.4.2]tetradecane dication) was obtained and characterized by X-ray crystallography, elemental analyses, and IR spectroscopy. In the polymer, a unique 1D helical chain of (Cu3I5)(n) cluster was constructed, and the C-H center dot center dot center dot I intermolecular interactions extended the 1D entities into high-dimensional frameworks to stabilize the supramolecular architecture. Furthermore, thermal property (TG, DTG and DSA) of the polymer was studied.

  DOI：

  10.1080/15533170903227812

文献信息

• Method for synthesizing spiro quartenary ammonium systems
  申请人：Siggel Alfred

  公开号：US20070049750A1

  公开（公告）日：2007-03-01

  A method for preparing a spiro quaternary ammonium system and electrolytes containing spiro quaternary ammonium cations, comprising a synthesizing step wherein a spiro ammonium system is formed in a medium that can serve as both the reaction solvent and as an electrolyte solvent.

  一种制备螺环季铵体系和含有螺环季铵阳离子的电解质的方法，包括合成步骤，其中在既可作为反应溶剂又可作为电解质溶剂的介质中形成螺环铵体系。
• US8426593B2
  申请人：——

  公开号：US8426593B2

  公开（公告）日：2013-04-23
• Self-Assembly, Crystal Structure and Thermal Property of a Coordination Polymer [(DDTD)(Cu₃I₅)]_n
  作者：Fu-Kai Zhao、Mei Liu、Xiao-Ling Guo、Dong-Hui Wei、Yun-Yin Niu、Hong-Wei Hou、Yao-Ting Fan、Ming-Sheng Tang

  DOI：10.1080/15533170903227812

  日期：2009.10.16

  A novel coordination polymer [(DDTD)(Cu3I5)](n)(DDTD = 5, 8-diazoniadispiro[4.2.4.2]tetradecane dication) was obtained and characterized by X-ray crystallography, elemental analyses, and IR spectroscopy. In the polymer, a unique 1D helical chain of (Cu3I5)(n) cluster was constructed, and the C-H center dot center dot center dot I intermolecular interactions extended the 1D entities into high-dimensional frameworks to stabilize the supramolecular architecture. Furthermore, thermal property (TG, DTG and DSA) of the polymer was studied.