methyl 7-methyl-9-oxo-9H-thioxanthene-3-carboxylate | 77084-51-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 硫色烯
• 英文名称: methyl 7-methyl-9-oxo-9H-thioxanthene-3-carboxylate
• 英文别名: methyl 7-methyl-9-oxothioxanthene-3-carboxylate
• CAS: 77084-51-6
• 化学式: C₁₆H₁₂O₃S
• 分子量: 284.335
• InChiKey: WGGQKDZZNOQMNU-UHFFFAOYSA-N

物化性质

• 沸点：
  470.0±45.0 °C(Predicted)
• 密度：
  1.315±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  68.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-硝基对苯二甲酸二甲酯 在 N,N-二甲基甲酰胺 氯磺酸 、 氯化亚砜 、 三乙胺 、 sodium hydroxide 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 5.5h， 生成 methyl 7-methyl-9-oxo-9H-thioxanthene-3-carboxylate
  参考文献：
  名称：

  [EN] LOW-EXTRACTABLE THIOXANTHONES
  [FR] THIOXANTHONES FAIBLEMENT EXTRACTIBLES

  摘要：

  3-硫代二苯酮的3-酯和3-酰胺，带有适当长度的烷基链，可用作光引发剂或感光剂，特别适用于制备与食品接触兼容的涂层。

  公开号：

  WO2012062692A1

文献信息

• LOW-EXTRACTABLE THIOXANTHONES
  申请人：Casiraghi Angelo

  公开号：US20130237628A1

  公开（公告）日：2013-09-12

  3-Esters and 3-amides of thioxanthone bearing alkyl chains of appropriate length and can be used as photoinitiators or sensitizers in photopolymerizable systems, in particular for the preparation of coatings compatible with the food use.

  3-硫代黄酮酮的3-酯和3-酰胺，带有适当长度的烷基链，可用作光引发剂或感光剂，特别适用于制备与食品使用兼容的涂层的光聚合系统。
• Low-extractable thioxanthones
  申请人：Casiraghi Angelo

  公开号：US08933142B2

  公开（公告）日：2015-01-13

  3-Esters and 3-amides of thioxanthone bearing alkyl chains of appropriate length and can be used as photoinitiators or sensitizers in photopolymerizable systems, in particular for the preparation of coatings compatible with the food use.

  3-巯基黄酮的3-酯和3-酰胺带有适当长度的烷基链，可用作光引发剂或感光剂，特别是用于制备与食品接触兼容的涂层的光聚合系统。
• Ink composition, inkjet recording method, printed material, and process for producing molded printed material
  申请人：FUJIFILM Corporation

  公开号：EP2042572A1

  公开（公告）日：2009-04-01

  An ink composition is provided that includes a perfluoroalkyl group-containing polymer, a polymerizable monomer, and a radical polymerization initiator, in which at least 80 wt % of the polymerizable monomer is a monofunctional polymerizable monomer selected from the group consisting of a monofunctional acrylate, a monofunctional methacrylate, a monofunctional vinyloxy compound, a monofunctional N-vinyl compound, a monofunctional acrylamide, and a monofunctional methacrylamide. There are also provided an inkjet recording method that includes a step of discharging the ink composition onto a recording medium and a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation, a printed material obtained by the inkjet recording method, and a process for producing a molded printed material that includes a step of forming an image by discharging the ink composition onto a support by an inkjet method, a step of irradiating the image thus obtained with actinic radiation so as to cure the ink composition and obtain a printed material having the image cured on the support, and a step of molding the printed material.

  提供了一种墨水组合物，它包括含全氟化烷基的聚合物、可聚合单体和自由基聚合引发剂，其中至少80重量％的可聚合单体是从单官能丙烯酸酯、单官能甲基丙烯酸酯、单官能乙烯氧基化合物、单官能N-乙烯基化合物、单官能丙烯酰胺和单官能甲基丙烯酰胺组成的组中选出的单官能可聚合单体。还提供了一种喷墨记录方法，该方法包括将墨水组合物排放到记录介质上的步骤，以及通过用阳极辐射照射排放的墨水组合物来固化墨水组合物的步骤，通过该喷墨记录方法获得的印刷材料、以及一种用于生产模塑印刷材料的工艺，该工艺包括通过喷墨方法将墨水成分排放到支撑物上以形成图像的步骤，用放电辐射照射由此获得的图像以固化墨水成分并获得在支撑物上固化了图像的印刷材料的步骤，以及模塑印刷材料的步骤。
• Photocurable coating composition, and overprint and process for producing same
  申请人：FUJIFILM Corporation

  公开号：EP2042564A1

  公开（公告）日：2009-04-01

  A photocurable coating composition is provided that includes an ethylenically unsaturated compound having an alicyclic hydrocarbon group and a photopolymerization initiator. There are also provided a process for producing an overprint, the process including a step of obtaining a printed material by printing on a printing substrate, a step of coating the printed material with the photocurable coating composition, and a step of photocuring the photocurable coating composition, an overprint produced by the process, use of the photocurable coating composition for producing an overprint, and use of the photocurable coating composition for producing an overprint for an electrophotographically printed material.

  提供了一种光固化涂层组合物，它包括具有脂环烃基团的乙烯基不饱和化合物和光聚合引发剂。还提供了一种用于生产叠印的工艺，该工艺包括通过在印刷基材上印刷获得印刷材料的步骤、用可光化的涂层组合物涂覆印刷材料的步骤、对可光化的涂层组合物进行光固化的步骤、由该工艺生产的叠印、使用可光化的涂层组合物生产叠印，以及使用可光化的涂层组合物生产电致发光印刷材料的叠印。
• Ink composition, inkjet recording method, printed material, and molded printed material
  申请人：FUJIFILM Corporation

  公开号：EP2088176A1

  公开（公告）日：2009-08-12

  An ink composition is provided that includes (A) a compound having an ethylenically unsaturated double bond and a silicone chain, (B) a polymerizable monomer, and (C) a radical polymerization initiator, at least 75 wt % of the polymerizable monomer being a monofunctional polymerizable monomer selected from the group consisting of a monofunctional acrylate, a monofunctional methacrylate, a monofunctional vinyloxy compound, a monofunctional N-vinyl compound, a monofunctional ethylenically unsaturated carboxylic acid compound, a monofunctional acrylamide, and a monofunctional methacrylamide. There are also provided an inkjet recording method that includes (i-1) a step of discharging the ink composition onto a recording medium and (i-2) a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation, a printed material formed by employing the inkjet recording method, and a molded printed material formed by subjecting the printed material to molding.

  提供了一种油墨组合物，它包括(A)具有乙烯基不饱和双键和硅酮链的化合物，(B)可聚合单体，和(C)自由基聚合引发剂，其中至少 75 wt % 的可聚合单体是选自以下组别的单官能团可聚合单体单官能度甲基丙烯酸酯、单官能度乙烯氧基化合物、单官能度 N-乙烯基化合物、单官能度乙烯基不饱和羧酸化合物、单官能度丙烯酰胺和单官能度甲基丙烯酰胺。还提供了一种喷墨记录方法，该方法包括（i-1）将墨水组合物排放到记录介质上的步骤和（i-2）通过用阳极辐射照射排放的墨水组合物来固化墨水组合物的步骤、通过使用喷墨记录方法形成的印刷材料和通过使印刷材料成型而形成的成型印刷材料。