[PuO2(1,10-phenanthroline)(benzoate)] [PuO2(C12N2H8)(OOCC6H5)], high temperature | 1214279-27-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: [PuO2(1,10-phenanthroline)(benzoate)] [PuO2(C12N2H8)(OOCC6H5)], high temperature
• 英文别名: [PuO2(1,10-phenanthroline)(benzoate)]
• CAS: 1214279-27-2
• 化学式: C₇H₅O₂*C₁₂H₈N₂*O₂Pu
• 分子量: 577.387
• InChiKey: FLKUWOCKFHTWPY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  26.0
• 可旋转键数：
  1.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  100.05
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  [PuO2(1,10-phenanthroline)(benzoate)] [PuO2(C12N2H8)(OOCC6H5)], high temperature 以 neat (no solvent) 为溶剂， 生成 plutonium(IV) oxide
  参考文献：
  名称：

  Synthesis and properties of complexes of Np(V) and Pu(V) benzoates with phenanthroline

  摘要：

  Complexes of 1,10-phenanthroline (phen) with Np(V) and Pu(V) benzoates of the compositions NpO2(phen)(OOCC6H5) and PuO2(phen)(OOCC6H5) were synthesized. A powder X-ray diffraction study showed that these compounds, depending on the preparation conditions, exist in the form of two phases having essentially the same composition but different powder patterns. The phases isolated from hot (70-100 degrees C) solutions are isostructural with the previously described complexes AnO(2)(bipy)(OOCC6H5) (An = Np and Pu, bipy = 2,2'-bipyridine), i.e., in their structure there are dimeric (AnO(2))(2)(2+) cations formed by mutual coordination of two AnO(2)(+) ions via "yl" oxygen atoms. The compounds AnO(2)(phen)(OOCC6H5) prepared by slow crystallization in the cold or at weak (up to 45 degrees C) heating are isostructural with each other but appreciably differ in the structure from the high-temperature phases. The electronic absorption spectra of the compounds and their thermal behavior were examined.

  DOI：

  10.1134/s1066362209030035
• 作为产物：
  描述：

  plutonyl(VI) perchlorate 、 1,10-菲罗啉 、 ammonium benzoate 以 水 为溶剂， 生成 [PuO2(1,10-phenanthroline)(benzoate)] [PuO2(C12N2H8)(OOCC6H5)], high temperature
  参考文献：
  名称：

  Synthesis and properties of complexes of Np(V) and Pu(V) benzoates with phenanthroline

  摘要：

  Complexes of 1,10-phenanthroline (phen) with Np(V) and Pu(V) benzoates of the compositions NpO2(phen)(OOCC6H5) and PuO2(phen)(OOCC6H5) were synthesized. A powder X-ray diffraction study showed that these compounds, depending on the preparation conditions, exist in the form of two phases having essentially the same composition but different powder patterns. The phases isolated from hot (70-100 degrees C) solutions are isostructural with the previously described complexes AnO(2)(bipy)(OOCC6H5) (An = Np and Pu, bipy = 2,2'-bipyridine), i.e., in their structure there are dimeric (AnO(2))(2)(2+) cations formed by mutual coordination of two AnO(2)(+) ions via "yl" oxygen atoms. The compounds AnO(2)(phen)(OOCC6H5) prepared by slow crystallization in the cold or at weak (up to 45 degrees C) heating are isostructural with each other but appreciably differ in the structure from the high-temperature phases. The electronic absorption spectra of the compounds and their thermal behavior were examined.

  DOI：

  10.1134/s1066362209030035